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Please login or sign up for a free trial to access the full content.1.4.4.14.3 The Inter- and Intramolecular Pauson–Khand Reaction
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Malacria, M.; Aubert, C.; Renaud, J.-L., Science of Synthesis, (2001) 1, 512.
The Pauson–Khand reaction generates a cyclopentenone in a single step from an alkyne via its hexacarbonyldicobalt complex, an alkene, and carbon monoxide, with the last present as a ligand in the complex or added as the gas (Scheme 87). The overall process of this reaction is a formal [2+2+1] cycloaddition. The reaction was discovered in 1973 during a study of the reaction of various (alkyne)hexacarbonyldicobalt complexes with norbornadiene.[208] Since then, this reaction has attracted considerable interest among synthetic and organometallic chemists, as evidenced by the number of publications in the last two decades. Excellent reviews have been published and have compiled all the aspects of this reaction in terms of scope and limitations, mechanism, regio- and stereoselectivities, examples in inter- and intramolecular versions, and several synthetic applications.[339–343,400–402]
Meeeee 88 Meeeeee Meeeee eee eee Meeeee–Meeee Meeeeeee
Mee eeeeeeeee ee eee eeeeeeee ee eee eee eeeee eeeeeeeeeee; eeeeeee, eee eeeeeeeeeee eeeeeeeeeeee ee eee (eeeeee)eeeeeeeeeeeeeeeeeeee eeeeeee, ee eee eeeee eeeee ee eee eeeeeee, eee eeee eeeeeeeeeeee. Meeee eeeeeeeeeeeee eeeee eeeeeeeeee eeee eeeeee ee eeeeee eeeee eeee eeee eeee eeeeeeee.[888] Me ee eeeeeee eeeeeee eeee eeeeeeeeeeee ee eee eeeeee ee eee eeeeee eeee eeeee eeeee eee e eeeeeeeeeeee eeeeeeeee eeeeeeeee eeeeeee eeee ee eeeeee eeeeeeee, eeee eeeeeee eeeeeeeee eeeee eeeeeeeeee (Meeeee 88). Meeeeeeeeeee, eeeeeeeeeeee eeeeeeeee ee eee eeeeee π-eeee eeee eee ee eee eeeeee Me—M eeeee ee eee eeeeee eeeeeee eeeeee, ee eee eeee eeee ee eeeeeeee eeee eeee eee eeeeeee eeeeeeeeeee, eee ee eeeeeeee ee eeeeeeee ee eeeeee eeeeeeee ee eee eeeeeeeeeeeeee eeeeeeeeeee eeeeee eeee. Mee eeeeeeeeeee eeee eeeee eee eeeeeee ee eee eeeeeee ee e eeeeeeee eeeeeeee ee eeeeeeeee eeeeeeeee ee e eeeeee-eeeee eeeeee eeeeeeee eeeeeeee, eeeeeeee ee eeeeeee eeeeee eeeeeeee eeeeeeee, eee eeeeeee e eeeeeeeee eeeeeeeeeee ee eee eeeeeeeeeeeeeeeee eeeeee. Mee eeeeeeeee eeeeeeee ee eee eeeeeeeeeeeeeeeeeeee eeeeeee ee eee eeeee eeeee eee eeee ee eee eeeeeeeeeeeeeeeeeeee eeeeee eeeeee eeeeee ee eeeee eeeeeeeeee ee ee eeeeeeeeee eeeeee eeeeeeeee eee eeeeeee.
Meeeee 88 Meeeeeeee ee eee Meeeee–Meeee Meeeeeee
Mee Meeeee–Meeee eeeeeeee eeeeeee eeeee eeee eeeee- eee eeeeeeeeeeeeeeeeeee. Meeee eeeeee eee eeeeeeeeeee eeeeeeeeee, eeeeee ee eeeeee eeeeeeeeeeee ee eee eeeeeeeeeeee eeeeee eeeeeeeee eeeeeee. Me eeeeeee, eee eeee-eeeeeeee eeee ee eee eeeeee eeeeeee eeee eee eeee-eeeeeeee eeeeee Me—M eeee ee eee eeeeeeee eeeeeee, eeee eee eeeeeeeeeee ee eeeeee eeeeeeeee eeeeeee eee eeeeee eeeeeee eeeeeeeeeee eeee eeee eeeeee.
Meeeee–Meeee eeeeeeeee eeee eeee eeeeeee eee eeeee eeeeeee eeeeeeee eeeeeeeee eeeee ee eeeeeeee eeeeeeeeee. Me eee eeee eeeeee eeee eeeeee eee eeeeeeeeeeeeee eeeeeeee, eee eeeeee ee eeeeeee ee eeeee eeee e eeeeeeeeeeeeee eeeeee ee eeeeeeeeeeeeeeeeeeee (88) ee eeee eeeeeeeeeee eee eee eeeeeee ee eeee eeeeee eeee eee eeeeee ee eeeeeeee eee eeeeeeeeeeeeee. Meeeeeeee eeeeeeeeeeeeee, eeeeeeeeeeeee ee eeeeeeeeeeeeee eeeeeeeee, eeee eeeeeeee eeee eee eeeeeeee ee eeeeeee ee eeeeee eee,[888] eeeeeeeee eeeeee,[888] eeeeeeee eeeee eeeeee,[888,888] eeeeeeee eeeeeeeee,[888] ee eeee eeeeeee eeeeee[888] eeeeeeeeeee eee eeeeeeee, eeeeeeee eee eeeeeeeeeee, eee eeeeeeee eeeeee eeeeee eeeee eeeeee eeeeeeeeee. Me eeee eeeee, eee eeeeeeee ee ee eeeeeeee ee e eeeeeeee eeeeee eee eee eeeeeeeee ee eeeeeeeeeeeeeee eeee eeee eeeeeeeeee ee eeeeee eeeee eeeeeee eeeeeeeeee.
Mee Meeeee–Meeee eeeeeeee ee eeeeee eeeeeeee ee eeee eeeeeeeeee eeeeee, eeeeeeeee eeeeee, eeeeeeee, eeeeeeee eeeeee, eeeeeeeeee, eeeeeee, eeeeee, eeeeee, eeeeee, eeeeeeee eeeee eeeeeeeee eeeeeee, eeeee, eee eeeeeeeee, eee eeee Meeeeee eeeeeee eeeeeeeee.[888,888] Mee eeeee ee eee eeeeeeee eeee eeeeeee ee eee eeeeeeeee eeeeeeeee ee eeee eeeeeeeeeeee. Meeee eeeeeee eeeeeeeeee, eee eeeeeee, eeeeee eeeeeeeeeee ee eeeeeeeee eeee, eeeeeeeeeee; eeeeeee, ee eeeee eee eeeeeeee eeeee M-eeeee eeeeeeee, eee eeeeeeee ee eeeeeeee ee eee eeeeee ee eeeeeeeeeee.[888] Meeeeeeee, eeeeee eeeeeeee eeeeeee eeeeeeeee eeeeeeeeeee, eee eeeeeeee eeeeeee eeeee eeee eeeeee ee eeee eeeeeeeeeeeeeee. Me eeeeeee eeeee, eeee ee eeeeeeee eeeeeeee eeeeeeeeee, eee eee ee eeeeeeeee ee eeeeeeeeee.
Me eeeeeeee, eee eeeee ee eee eeeeeeeeeeeeee eeeeeeee eeee eeeeeee ee eee eeeeee ee eeee eeeeeee (Meeeee 88). Meeeeeee eeeeee eeeeeee eee eee eeee eeeeeeeeee, eeeeeeeee eeeeeeee ee 88–88°M eeee e eeeeee ee eeeeeee eeeee. Meeeee eeeeeeeee eeeeee eee eeeeee eeee, eeeeeeeeeeee eee- eee eeeeeeeeeeeeeeee eeeeee eeeee eee eeeeee eeeee eeeeeeeeee eeeee eeeeeee eeeeeeeeeeee, eeeeeeeeee eeeeeee ee eeeeeeeeeeeeeee ee eee eeeeee. Meee eeeeeeeeee, eeeeeee eeeeeeeeee ee eeeeeeee-eeeeeeeeeee eeeeeeeeeeee eeeee eeee eeeeeeeeeee eee eeeeeee 8,8-eeeeee.[888] Meeeeeee, ee eee eeee eeeeeeee eeee eee eee ee M-eeeeeeeeeeeeeeee eeeee ee e eeeeeeee ee eee eeeeeeee eeeeee eee eeeeeeeee ee eeeeeeeeeeeeeee.[888] Meeeeee eeee eeee eeee eeeeeeee ee eeee eeeeeeee ee eee Meeeee–Meeee eeeeeeee.[888]
Meeeee 88 Meee Meeeeeee ee eee Meeeeeeeeeeeee Meeeee–Meeee Meeeeeee[888]
Meeeee eeeeeee eee eeeeeeeeee eeeeee eeeeeee eee eeee eeeeeeeee eeee eeeeeeeeee ee eeeeeeeeeeeeee eeeeeeeee. Meeeeeeeee eeee ee eeeeeeeeeeeeee eeeeeee eeeeeee eee Meeeee–Meeee eeeeeeee eeeeeeee ee eeee eeeeee. Meeeee, eee eeeeeeeeeeeeee eeeeeeee eee eeeee eee eeeee eeeeeeee eeeeeeeeeeee eeeeeee eee e eeeeee eeeeee. Meeeee ee eeeee eeeee ee eeee eeeee eeeeeeee eee eeeeee eee eeeeee eeeee eeeeeee eeee eeeeeeeeeeee ee eeeeeeeeeeeeeeeeeeee (88) eee eeeeee eeeeeeeeee eeeeeee ee eeeeeeeee eeee eeeeeeeeeee eeeeeeeee ee eeee eee eeeeeeee eeeeee. Mee-8-ee-8-eee, eeeee eeeee eeeeeeee eeee e eeee-eeeeeeee eeee, eeeeeeeee eeeeee eeeeeeeeeeeeeeeeee eeeeeeeeeee.[888] Me eee eeeeeeee, eeeeeee[8.8.8]eee-8-ee-8-eeee, eee eeeeee ee eee eeeeeeeee ee eeeeeeee eeeeeeeeeeee-eeeee eeeeeeeeee eeeeeeeee, eee eeee eeeeeeeeeee eeeeeee eeeeeee eee eeeee eeeeeee eeee eeee-8-ee-8-eee. Mee eeeeeee eeee eeeeeeeeee ee eee eeeeeeeeeeeeeeeeeeee ee eee eeeeeeeeeeeeee eeeeeeeee, ee eeee ee eee eeeeeee ee eee eeeeeeeeeeee ee eeeeee eee ee eeeeeeee eeeee, eeee eee eeee eeeeeeee.[888,888–888] Mee eeeeeee ee eee eeeeeeeeeeee ee eee eeeeeeeeee eeee eeee e eeeeeeeee eeee ee ee eee eeeeeeeee eeeeeee eeeeeeeee ee eeee eeeeeeeeee eeeeeeeee eee eee eeeeeeeeeeeeee eeeeeeee. Meee ee ee eee eeeeeeeeeeeeee eeeeeee, eee eeeeeeeeeeeeee Meeeee–Meeee eeeeeeeee eee eeeeeee eee eeeee eeeeeee eeeeeeeeee. Me eeee eeeee, eeeeeeeee eeee eeeee eeeeee eeeeeeee eee eeeeeeee eeeee eee eeeeee eeeeeee eeeeeeeeeeeeeeeee eee eeeeeeee eeeeee. Me eee eeee eeee eeeeeeee eeee eee eeeeeeeeeeeeee eeeeeeee ee eeeeeeee-eeeeeeeee eeeeeee eeeeeeee eeeeeeee ee eeee eee eeeeeeeeeeeee eeeeeeee eeeeeeeee ee eeee eeeee eeee eeeeeeeeeeee ee eeee ee eee eeeeeee.[888] Mee eeeeeeeeeeeeee eeeeeeee ee eee eeeeeee ee eeeeeee eee-eeeeee eeeeee. Meee, eee eeeeeeeee ee eeeeeee eeeeee eeeeeeeeee eeeeeeeeeee (eeeeee,[888] eeeeeeee,[888] ee eeeeee[888]) eeeeeee eee eeeeee eee eee eeeeee eeee ee eeee (Meeeee 88). Meeeeeeee eeeeeeeee eeeeee eeeeee eeee eeee eeee eeeeeeee eee, ee ee eeeeeeeeeeeeee eeeeeeee, eee [8+8+8] eeeeeeeeeeeee ee eeeeeeeee ee eeeee eeeeeeeee.[888,888]
Meeeee 88 Meeeeeee Meeeeeee ee eee Meeeeeeeeeeeee Meeeee–Meeee Meeeeeee[888]
Meeeeeeeee ee eeeeeee eeeeeeeeee eeeee- eee eeeeeeeeeeeeee Meeeee–Meeee eeeeeeeee eeee eeee eeeeeeeee. Mee eeeeeeeeee eee eee eee ee eeeeee eeeeeeeeeee eeeeeeee eeeee ee eeeeee ee eee eeeeeeeeeee eeeeeeee[888,888] ee eee eeeeeeeeee ee eeeeeeeee eeeeeeeeee e eeeeeeeeeee M8Me8 eeee; eeeeeee, eeee eee eeeee ee eeeee eee eeeee eeeeeeeeeee ee eee eeeeeeeee ee eeeeeee eeeeeeeee. Meee, eeee eeeeeeeeeeeeeeeeeeeeee (88% ee) eeee eeee eeeeeeee ee eeeee 88-(eeeeeeeeeeeee)eeeeeeeeee eeeeeeeeeee ee eeeeee eeeeeeeeeee (Meeeee 88). Meeeeeee, ee eee eeee eeeeeeeeeeee eeee eee eeeeeeee eeeee eee eeee ee eeee ee e eeee eeeeeeeee eeeeee eeeeeeeee. Meeeeeeeeee eeeeeeeeeeeeeeeee (>88% ee), eeeeeee eeee ee eeeeeeeee eeeee eeeeee eeeeeeeee eeeeeeeeeee eeee, eee eeeeeeeee.[888] Meeeeeeee eeee M-eeeeeeee-eeeee 8,8-eeeeee ee eeeeeeeeeeee eeeeeeeee eeee eeee eeee eeeeeeee ee eeeeee eee eeeeeeeeeeeee eeeeeeeeeeee ee eeeeeeeeeeeeeeeeee eeee eeee.[888] Mee eee ee eeeeee eeeeeee eeee ee eee eeeeee eeeeeeeee eeeeee “eeeeeee” eee eeeeeeee eee eeee eeeeeeeeeeeeeee eeee eeeeeeee ee eeeeeeeee eeeeeeeeeeee eeeeee.[888,888] Mee eee ee eeeeee eeeeeeee eeeee eeeeee eee eeee eeeeeeee, eee eeee eeeeeee eeeeeee.[888]
Meeeee 88 Meeeeeee Meeeeeee ee eee Meeeeeeeee Meeeee–Meeee Meeeeeee[888,888]
Meeeeeee eeee eeee eeee ee eeeeeee eee Meeeee–Meeee eeeeeeee eeeeeeeeeeeee, eeeee e eeeeee eeeeeeee eeeeeeeeee, eeee eeeeeeee eeeeeee. Meeeeeeee eeeeeeee eeeeeee eeee eeee eeeeeeeee eee eeeeee eee eeeeeeee eeeeeee eeee eeee eee ee eee eeeee ee eee eeeeeeee eee eeeeeee ee eee eee ee eeeeee ee eee eeeeee eeeeeee. Mee eeeee eeeeeeeee eeeeeeeee Meeeee–Meeee eeeeeeee eeeeeeee eeee eeeeeeeee eeeeeeeee ee eee eeeeeeee eee 8,8-eeeeeeeeeeeeeee ee eeeeeee (Meeeee 88); eee eeeeee eeee eeeeeeee eeeee eeeeeee eeeeeeee ee eeeeee eeeeeeee eee eeee eeeeeeeeeeeee eeeeeeee ee eeeeeeee eee eee eeeeeeee eeeee 8 eeeeeeeeeee ee eeeeee eeeeeeee.[888] Meeeeee eeeeeeeeeee eee eeeeeeeee eeeee 8,8-eeeeeeeeeeeeeee eeeeeeeeee eeee e eeeee eeeeee ee eeeee eeeee e eeeeeeee ee 8 eeeeeeeeeee ee eeeeee eeeeeeee.[888] Mee eeeeeeeee eeeeeee ee eee eeeeeeeeeeeeee eeeeeeee eee eeee eeee eeeeeeeee eeeee eeeeeeeeeee eeeee ee 88–88°M eeeee eeeeeee eeeeeeee ee eeeeee eeeeeeee, eee eeee eeeeee eeeeeeee eee eee ee eeee-eeeeee eeeeeeeeeeeeeeeeeeeee(8) (88).[888]
Meeeee 88 Meeeeeeee Meeeeeee ee eee Meeeee–Meeee Meeeeeee[888–888]
Meee eeeeeeeeee eeeeeee eeee eeee eeeeeeeee eee eee eeeee- eee eeeeeeeeeeeeee Meeeee–Meeee eeeeeeee, eee eeee ee eee eeeeeee eee eee ee 88. Meeee eeeeeee: (8) e eeeeeeeee eeeeee eeeeeeeee e eeeeee(M) eeeeeee eeee ee eeeeeee eeeeee eee 8,8-eeeeeeeeeeeeeee ee eee eeeeeee eeeee 88 × 888 Meee ee eeeeee eeeeeeee,[888] (8) e eeeeee eeeeeeeee e eeeeeeeee eeeeee ee eee(eeeeeeeeeeeeeee)eeeeee(MM) eee eeeeee eeeeeeeeeee,[888] eee (8) e eeeeee eeeee e eeeeeeeeeeeeeeeee eeeeee ee eeeeee(MM) eeeeeee, eeee, eee eeeeee eeeeeeee (888 Meee) ee 88°M ee e eeeeeee ee eeee-eeeee eeeeeee eee eeeeeeeeeeeeeee.[888]
Meeeeee, eeeee ee eee eeeeeeeeeeee eeeeeeeeee, eee eeeeeeeeee eeeeeeeee, eee eee eeeeeeeeeee eeeee- eee eeeeeeeeeeeeee eeeeeee, eee Meeeee–Meeee eeeeeeee eee eeeeeeeeeeee eeeee eeeeeeeeee eee ee eeeee eeeeeeeee; eeeeeee, eee eeeeeeeeeeee eee eee eeeeeeee ee ee eeeeeeeee eeee. Meeeee eee eeeeeeee e eeeeeeeeeeeee eeee ee ee 8888 ee eee eeeeee.[888] Mee eeeee eeeeeeeeeeee eeeee eeee eeee eeeeeee eee eeeeeeeee ee eeeee eeeeeeeee B-eeeeee eee eeeeeeeee eeeeeee,[888] eee eeeeeeeee ee eee eeeeeee eeeeeee,[888] ee eeeeeeee ee eeeeeeeeeeeeeeeeeee,[888] eee eeeee eeeeeeeee ee (+)-eeeeeeeeeeeeee,[888] ee eeeeeeeeee eeeeeeee ee (+)-B-eeeeeeeeee,[888] eee eee eeeeeeeee ee (±)-eeeeeeeeeeeeeeeeeeeeeeee.[888]
Meeeeeeeeeee Meeeeeeee
Meeeee–Meeee Meeeeeeee; Meeeeee Meeeeeeee:[888,888]
Meeeee M: Meeeeee eeeeeeeeeeeeee eeeeeeeeeeee; eeeeeeeeeeeeee eeeeeeeeee.
Me e eeeeeee eeee ee eee eeeeeee (eeeeeeeee eeeeee eeeeeeeee eee eeeeee ee Meeeeee 8.8.8.8 ee ee eeee) (8 eeee) ee eeeeeee ee MMM (8 eM) eee eeeee eee eeeeee (8 eeee) ee eeeeeee ee MMM eeee (8 eM). Mee eeeeeee eee eeeeee ee 88–88°M eeeee eee eeeeee eeeeeee eeeeeeeeeee, ee eeeeeeeeee ee MMM eeeeeeee (88 e ee 8 e). Meeee eeeeeeeeee eeeeeee e eeeee eee ee eeeeee eee eee eeeeeee ee eee eeeeeeee eeeee eeeeeee eeeeeeee, eee eeeeeee eeeeeeee eeee eee eeeeeee eeeeeeeeeeeeee eeeeeee eeeeeeeee eeeee eeeeeeeeeeeeee.
Meeeee M: MMM-eeeeeeee eeeeeeeeeeeeee eeeeeeeeeeee.
M eeee ee eee eeeeee eeeeeee (8.888 eeee) ee MM8Me8 (8 eM) eee eeeeeee eeee e eeeeee eeeeeee ee eeeee MMM (8.88 eeee, 8 eeeee) ee ee. Meeee 88 e ee ee, e eeeeee eeeeeeeeeee eee eeeeee, eee MMM eeeeeeee eeeeeeeee eee eeeeeeeeeee ee eee eee eeeeeeee eeeeeeee eeee eeeeeeeeeee eeeeeeeee ee e eeee eeeee eeeeeee. Mee eeeeeee eee eeeeee eeeeeee e eeeee eeee ee eeeeee eee eee eee eeeeeeee eee eeeeeeeeeeee ee eeeee. Mee eeeeeee eee eeeeeeee ee eeeee eeeeeeeeeeeeee ee eeeeee eee eeeeeeeeeeeee eeeeeeeeeeeeee.
References
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) M 88e, 8888.


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text:
1Axasiya nga Atalaya to a to a xa di bara faxa, a naxa natɛ tongo a xa mangɛ bɔnsɔɛ birin faxa.
2Kɔnɔ Yehoseeba, mangɛ Yorami xa di ginɛ, Axasiya fan maaginɛ, naxa Axasiya xa di Yowasi tongo mangɛ xa die ya ma, alako Atalaya naxa a tan faxa alɔ booree. Yehoseeba naxa sa a nɔxun konkoe nde kui, a nun dingɛ naxan ɲɔxɔ nu saxi a xɔn.
3E naxa lu naa Alatala xa hɔrɔmɔbanxi kui ɲɛ senni, Atalaya xa mangɛya bun ma.
4A ɲɛ solofere nde ra, Yehoyada naxa xɛɛra ti Karikae xa sɔɔri mangɛ nun mangɛ makantɛe ma. A naxa e raso Alatala xa hɔrɔmɔbanxi kui, e fa saatɛ gundo daaxi xiri e bore tagi naa. Na dangi xanbi, a naxa mangɛ xa di masen e bɛ.
5A naxa yi yaamari so e yi ra, a naxɛ, «Wo yi nan nabama. Wo tan naxee walima malabui lɔxɔɛ, wo xa wo itaxun dɔxɔ saxan na. Dɔxɔ keren xa mangɛ xa banxi makanta,
6dɔxɔ firin nde xa sa Suru naadɛ makanta, dɔxɔ saxan nde xa naadɛ makanta mangɛ makantɛe xanbi ra. Wo xa mangɛ xa banxi makantafe masara wo boore tagi.
7Sɛɛti boore firinyi, naxee mu walima malabui lɔxɔɛ, nee tan xa Alatala xa hɔrɔmɔbanxi makanta a fanyi ra mangɛ nɔxunxi dɛnnaxɛ.
8Wo mangɛ rabilinma nɛ, geresosee ra wo yi. Mixi yo a maso wo ra, wo a faxa. Wo xa lu mangɛ fɛ ma, a na siga dɛdɛ.»
9Sɔɔri xunyi naxee tixi sɔɔri kɛmɛ xun na, e naxa sɛrɛxɛdubɛ Yehoyada xa yaamarie rabatu, alɔ a a falaxi ki naxɛ. Kankan naxa a xa sɔɔri mixi kɛmɛ dɛntɛgɛ Yehoyada bɛ, naxee nu walima malabui lɔxɔɛ, nun naxee mu nu walima na lɔxɔɛ.
10Sɛrɛxɛdubɛ naxa mangɛ Dawuda xa tanbɛe nun kanke makantasee so sɔɔri xunyie yi ra, naxee nu ragataxi Alatala xa hɔrɔmɔbanxi kui.
11Mangɛ makantɛe naxa geresosee tongo, e naxa ti kelife Alatala xa hɔrɔmɔbanxi yirefanyi ma han a kɔɔla ma, sɛrɛxɛbade nun banxi fɛ ma, alako e xa mangɛ makanta.
12E to ti naa, Yehoyada naxa mangɛ xa di ramini, a mangɛ tɔnxuma dusu a xun na, a munyaati so a yi ra. A naxa ture sɛniyɛnxi surusuru a xunyi, a a ti mangɛ ra. Ɲama naxa e bɛlɛxɛe bɔnbɔ, e nu a fala e xui itexi ra, «Kisi na mangɛ bɛ!»
13Atalaya to mangɛ makantɛe nun ɲama xui mɛ, a naxa siga e yire Alatala xa hɔrɔmɔbanxi.
14A naxa a to, mangɛ tixi hɔrɔmɔbanxi kinki fɛ ma, alɔ mangɛe darixi a ra ki naxɛ. Mangɛ makantɛe tixi mangɛ fɛ ma, e sarae fema. Ɲama birin nu sɛɛwaxi, e sarae xui raminima. Atalaya naxa a xa sosee ibɔɔ a yɛtɛ ma sunnunyi kui, a gbelegbele, «Yanfanteya! Yanfanteya!»
15Na kui sɛrɛxɛdubɛ Yehoyada naxa sɔɔri kɛmɛ xunyie yamari, «Wo a ramini hɔrɔmɔbanxi fari ma sɔɔrie yire. Mixi yo na wa a malife, wo na kanyi faxa santidɛgɛma ra.» Sɛrɛxɛdubɛ mu nu wama a xa faxa Alatala xa hɔrɔmɔbanxi kui.
16Sɔɔrie naxa a suxu, e a xanin mangɛ xa banxi kui kira ra soee soma dɛnnaxɛ ra, e a faxa mɛnni nɛ.
17Yehoyada naxa saatɛ xiri Alatala, mangɛ, nun ɲama tagi, a falafe ra e birin xa bira Alatala fɔxɔ ra.
18Bɔxi ɲama birin naxa so Bali kuye xa banxi kui, e sɛrɛxɛbadee nun kuyee kana. E naxa Bali kuye xa sɛrɛxɛdubɛ Matan faxa sɛrɛxɛbade fɛ ma. Yehoyada sɛrɛxɛdubɛ naxa sɔɔrie ti, naxee Alatala xa hɔrɔmɔbanxi makantama.
19A naxa sɔɔri kɛmɛ xunyie tongo, Kari sɔɔrie, mangɛ makantɛe, nun bɔxi ɲama birin, e fa mangɛ mati kelife Alatala xa hɔrɔmɔbanxi han mangɛ banxi. E naxa so mangɛ banxi kui mangɛ makantɛe xa naadɛ ra. Mangɛ Yowasi naxa a magoro mangɛ kibanyi kui.
20Bɔxi ɲama birin nu na sɛɛwɛ nun sabari nan kui, barima Atalaya nu bara faxa santidɛgɛma ra mangɛ banxi kui.

robotstxt: allowed

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text:
🌍Farafina Ngun kunafoniw Sanga kelin kono
🇪🇹Ethiopi: Gofɛrɛnaman ka laɲini ye ka awiyɔnbonda ni fédéral ka fɛnsɔrɔsiraw nafama wɛrɛw minɛ jamana woroduguyanfan fɛ
🇹🇳Tunisie: Lakanali kelaw ni lakanabagaw ye gniongon gniongon gniemogow Tunis djamana djekoulou kono
🇹🇩Tchad a min kɛra waati jan kɔnɔ salon, o kɔfɛ, Cad jamana na, sanjiba min nana waati kɔnɔ
🌍Farafina Ngun kunafoniw Sanga kelin kono
🇪🇹Ethiopi: Gofɛrɛnaman ka laɲini ye ka awiyɔnbonda ni fédéral ka fɛnsɔrɔsiraw nafama wɛrɛw minɛ jamana woroduguyanfan fɛ 🇹🇳Tunisie: Lakanali kelaw ni lakanabagaw ye gniongon gniongon gniemogow Tunis djamana djekoulou kono 🇹🇩Tchad a min kɛra waati jan kɔnɔ salon, o kɔfɛ, Cad jamana na
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Dunia Ngun Kunafoli Sanga kelin kono
🇷🇺Russie: Jamanatigi Vladimir Putin ye kuma ta bolonɔbila seli dɔ la, min tun bɛ Ukraine jamana naani minɛni seli la
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🇧🇫Burkina Faso: Marifa caman ani bɔgɔdaga dɔ mɛnna jamanakuntigi ka so kɛrɛfɛ, faaba kɔnɔ
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text:
Лani
Nin kera ce dɔ ye min tɔgɔ tùn ye Sibiri ye. A Wulila ka Bɔ màsabugu la k’a be na baara ɲini golodugu la. Tle tan ni duuru a be yaala la ʃiyɔrɔkola. A tùn b’i Da sugu kɔnɔga-kɔrɔlaw la.Wari min tùn b’a kùn a y’o Dun ka ban. A dònfini bԑԑ Nàna Ban pew. Aa !! ko in Nàna Sibiri kɔnɔ Gàn, A Tora tèn a t’a Dɔn a bɛ min Kɛ. Sibiri Nàna Dòn donnita la, hali o yԑrԑ la, a tùn be warinin min sɔrɔ o fana t’a Balo. Kɔngɔ ni sege ye Sibiri Fàsa fo k’a Halaki. Sibiri ye Sàn fila K’o la. O waati, tuma dɔw la denmisԑnninw be Bòli a nɔfe u b’a fɔ:
fatɔ fatɔ.... U tùn b’a Bon ni gɔngɔrɔw ye Sibiri be Bòli k’i Dogo. A b’I Kanto :
-E Ala ne ye mun ke ? I te Hine ne la wa? I te here dɔ Ke n ye wa?
Aa !! Sibiri Лaanina ka ɲani. Don dɔ la, a ni cekɔrɔba dɔ Bԑnna o y’a Ye min kԑ, a hine y’o Mine o y’a Weele k’a Ladi k’a ka Segin a fàso la, k’a ka Taa cikedugukolo dɔ Лini ni ka ci Kԑ k’a ka k’a ka hԑrԑsɔrɔsira ɲuman y’o de ye.
O Fɔ cԑkɔrɔba fԑ, Sibiri Taar’i Sìgi k’i miiri, ko bari o de bԑ ɲɔ Kԑ dlɔ ye. Hakilina caman Nàna a ma minnu ye cԑkɔrɔba ka kumaw Sɔn ‘ji la. Ɔ, o min Kɛra sa, A Seginna ka Nà masadugu la tun. A nàlen, a m'a Лɛsin foyi wɛrɛ ma sɛnɛ 'kɔ. A Nàna taari kelen ni tla Dàn tiga la, ka taari fla ni tla Dàn kàba la, ka taari kelen Dàn ʃɔ̀ la ani taari tlancɛ Dàn je la. A y'o fòro ninnu Baara kà Лὲ, fo mɔgɔw tɛmɛtɔ tùn bɛ Kabakoya, w'a a yere Nisɔndyara a ka dànnifɛnw wuliko la haali. Aa! ɲɔtigɛ Nàna Kɛ Sibiri y'i tɛgɛ Da balo kan fo ka feereta caman Blà o kɛrɛ fɛ. O kɛlen, a y'a ka balo Bɔ a la ni k'a tɔ Feere ka bagan caman Sàn ka dagabannaso kelen Jɔ ka sɔrɔ ka muso kelen Furu. Sibiri kɛlen Flɛ bànna ye sàn fla 'kɔnɔ tèn. O kɛlen, a tùn bɛ to ka denmisɛnninw Ladi k'u ka dɔ Bɔ tunŋalataa la k'u ka dugukolo Labaara ko bari dugukolo tɛ màa Nɛgɛ.
N y'a Tà yɔrɔ min, n y'a Blà yen.
Blàdon : 2017-04-06 Yɛlɛmako laban : 2017-04-06


text:
You are using Science Of Synthesis as a Guest.
Please login or sign up for a free trial to access the full content.25.1.2.2.2 Variation 2: Oxidation with Activated Dimethyl Sulfoxide and Related Species
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Podlech, J., Science of Synthesis, (2007) 25, 33.
Utilization of dimethyl sulfoxide as the oxidant in the presence of a suitable electrophilic activator is one of the most frequently used methods for the oxidation of primary and secondary alcohols to aldehydes and ketones, respectively.[2,6,55–58] Although some of the information given here has been gained from the syntheses of ketones, it relates to aldehydes as well. Two general features of all variations of this method are that no overoxidation to carboxylic acids is observed and diols are oxidized to 1,2-dicarbonyl compounds rather than cleaved oxidatively [as may occur when chromium(VI), manganese(VII), or ruthenium oxidants are employed]. Moreover, these variants use inexpensive and commercially available reagents and work both on small and large scales. Although many activation methods are recommended, only a fraction give constantly good results and these are the ones in common use. The first of them is the Swern method that traditionally employs oxalyl chloride as the activating agent. Acetic anhydride, trifluoroacetic anhydride, sulfur trioxide–pyridine, and others find occasional application in this role as well. The Corey–Kim method using dimethyl sulfide/N-chlorosuccinimide is included in this section since it and the Swern approach proceed through an identical intermediate. A comparison of the most frequently applied Swern-like methods has been published; however, the results obtained may be biased since they refer to the oxidation of just one substrate (decan-1-ol) (see Table 1).[59] Problems that occur with some of the methods are incomplete conversion, the formation of acetoxy- or chloro-substituted side products, and the generation of varying amounts of Pummerer products; the latter arise especially at higher temperatures. In addition, as the foul-smelling byproduct dimethyl sulfide is formed in all of the procedures, the reactions should be carried out in well-ventilated hoods and the solvent waste should be treated with bleach.
Meeee 8 Meeeeeeee ee Meeee-8-ee eeee Meeeeeee Meeeeeeee ee Meeeeeee Meeeeee ee eee Meeeeeee ee Meeeeeeee Meeeeeeeee Meeeee[88]
e e.e. = eee eeeeeeee.
e MMMM eee eeeeeee.
Mee eeeeeeee eeeeeeee eeeeeeeee eeeeeeeee eeeeee (Meeeeeee–Meeeee eeeeeeeee) eeee 8,8-eeeeeeeeeeeeeeeeeeeeeeee ee eee eeeeeeeeee eeeee[88] eee, eeeeeeee eeee ee eee eeeeeeeee ee eee eeeeeeee eeeeeeee eee ee eeeeeeee eee e eeee eeeee ee eeeeeeeeee eeeeee (eeeeeeeee eeee-eeeeee eeee-eeeee eeeeee) eee eeeeeeeeee eeee eee eeeeeeeeee,[88] ee ee ee eeeeee eeeeeeeee eeee eee eee eeeeeeeee ee eeeeeeee. Mee eeeeeeee eeee ee ee eeeeeeeee eeee eeee eeeeeeeeeee. Meeeeee, eeeeeeeeee ee eee eeeeeeeeeeee eeee e eeee eeee (e.e., eeeeeeeeee eeee, eeeeeeeeeeeeeee eeee, ee eeeeeeeeeeeeee eeee) ee eeeeee, eeeee eeee eeeee eeee eee eeeeeeee ee e eeee ee eeeeeeee eeeeee eeeeee. Meeeee 8,8-eeeeeeeeeeeeeeeeeeeeeeee ee eeeeeeeee ee eeeeeee e eeeeeeeeee eeeeeeee eeee eee, eeeee eee eeeeeeeee, eeee ee eeeeeeeeeee ee eeeeeee eeeeeeeee eeee eeeeee eeee, eeeee eeeee ee eee eeeeeeeee ee 8,8-eeeeeeeeeeeeeeee, eeeeee eeeeeee, eee eeeeee eeeeeeee. Meeeeeeeeeeee, eee eeeeeeeeeeeeeeee, eee eeeeeeeeeee eeeeeee ee (eeeeeeeeeeeeee)eeeeee eeeeee eeee eee eeee eeeeee, eeeeeeee eeeeeeeee eeeeeeeeee. Mee eeeeeeeee ee 8,8-eeeeeeeeeeeeeeee eee ee eeeeeee ee eeeee eeee eeeeeeeee eeeeeee-eeeee ee eeeee-eeeeeee eeeeeeeeeeeee {e.e., M′-[8-(eeeeeeeeeeeee)eeeeee]-M-eeeeeeeeeeeeeeeee eeeeeeeeeeeee, MMM}.[88] Meeeeeee, eeee eeeee eeeee eeeeeeee e eeeeeee eeeeeee eeeeeeeee eeeeeee eee ee eeeeeeee; eeeeee, eeeeeeee eeeeeeee ee eee eeeeeeeee eeee eeeeeeee eeeeeeeeeeeeeeeeeeeeeeee.
Mee Meeee eeeeeeeee, eeeee eeeeee eeeeeeee ee eee eeeeeeeeee eeeeeeeeeeee, ee eee eeee eeeeee eeeeeee ee eee eeeeeeee eeeeeeeee eeeeeeeee-eeee eeeeeeeee.[88,88–88] Meee eeeeee ee eeeeeeeee, eeee ee eeeeeee [88, M8 = (MM8)8Me] (Meeeee 88),[88,88] eee eeeeeeee eeee eeee eeeeee eee eee eeeeeeee eee eeeeeeeeeee eee eeeeeeee. Mee eeeeeee eeeeeee, ee ee eeeeeeeeeeee ee eeeeeee eeeeee eeeeeeee eeeee ee eee. Mee eeee eeeeeeee eeeeeeee eee eeeeeeeeeeeeeee eee eeeeeeeeeeeeeee, eee eeeeee eeee eeeeee eeeeeeee eee eeee ee eeee.[88] Meeeeeeeeeee ee eee eeeeee eeeeeee eeee eeeeeeee eeeeeeeee eee eeeeee eeeeeeee ee eeeeeeeee ee eee eeeeeeeeeee (eeeeeee eeeeeee −88 ee −88°M) eee eee eeeeeee ee eeeee ee eeee ee ee e eeeeeeee eeeeee eeeeeeeeeee. Meeeeeeeeeee, eeeeee eeeeeeee eeeeeeeeeeee eee eeeeeeee ee eeeeeee eee eeeeeeeeee ee eeee eeeeeeee eeeeeeeeee (eee eeeeeeeeee-8-ee,[88] Meeeee 88); eeeeeee, eeeeeeee eeeeeee eeeeee eee eeeeeeee ee ee −88°M, ee eeeeee eeeeeeeeeeee (8°M) eee eeeee eeeee eeeeeeeeeeeee.[88] Mee eeeeeeeee ee eeeeeeeee ee eeeeeeeeeeeee eee eeeeeeeee eeeeeeeeeeee ee eee eeeeeeee ee ee eeeee eeee (eeeeeeeee eeeeeeeeeeeee), eeeee ee eee eeeeeeeeeee. Meee eee eeee eeee ee eeee eeeeeeeeeeeeeeeeeee ee ee a-eeeeee eeeeeeee ee eeeeee, eee eeee eeeeeee eee eeeeeeee ee eeeeeee.[88] Mee eeeeeee, eeeeeeee eeeeeeeeeeeeeeee eeee 8-(eeeeeeeee)eeeeee-8-ee ee eeeeeeee eeeee eeeeeeee eeeeeeeeee ee eeee eee eeeeeeeeeeeee eeeeeeee eeee eeeee 8% eeeeeeeeeeee eeee eeeeeeeeeeeee ee eeee ee e eeee,[88] eeee eeeeeeeeeeee ee eeeeeeeeee eeee M,M-eeeeeeeeeeeeeeeeeeeee ee eeee eeeeeee.[88] Meeee eee eeeeeeeeeeeeee eeeeeeeeee (MM, MM8, eee MMM) eee eeeeeeee eee eeee eeeee eeeeeee (<8%) ee (eeeeeeeeeeeeee)eeeeee eeeeee eee eeeeee ee e Meeeeeee eeeeeeeeeeeee, eeeeee ee eeeeeeeeeeeee eeeeee. Meeeeeee ee eeeee eeeeeee, eee Meeee eeeeeeeee ee eee eeeeeeee eeeeeeeeee ee eeeeee eeeeeee.[88] Meee ee eeeeeeeeeee ee eee eeee-eeeeeeee eeeeeeeee ee 8-eeeeeeeeeeeeeeeee ee eee eeeeeeee (Meeeee 88).[88,88] Meeeeeeee eeeeee ee eeeeeeeeee eee eeeeeeeeeeee eeeeeeeee eeee eeeeeeeee eeeeeeeeee eee eeeeeeee. Me eeee eeeee, eeeeee eeeeeeeeeeeeeeeee ee eeeeeeeeeee ee e eeeeeeeeee eee eeeeee eeeeeeee. Meee ee eeeeeeeeee eeeeeeeee ee eee eeeeeeeee ee 8-eeeeeeeeeeeee eeeee eeeeeeee eeeeeeeee/eeeeee eeeeeeee eeeee eeee e 88% eeeee ee eee eeeeeeee eeeeeeee ee e 88% eeeee eeee eeeeeeee eeeeeeeee/eeeeee eeeeeeeeeeeeeeeee ee eeee.[88]
Meeeee 88 Meeee Meeeeeeee ee Meeeeee Meeeeeee eeee Meeeeeee Meeeeeeee/Meeeee Meeeeeee/Meeeeeeeeeeee[88,88,88,88]
e e.e. = eee eeeeeeee.
e Meeeeeeeee ee eee 8,8-eeeeeeeeeeeeeeeeeeeeee.
e Mee eeeeeee eee eeeee ee eee eeeeeeeee eeeeee eeeeeee ee −88°M.
e Mee eeeeeeeeeee eee eeeee ee eee eeeeeeeeeee ee 8-eeeeeeeeeeeee eee eee eeeeeeeee.
Me eeeeeeeeeeee eeeeeeeee eeeeeeeee ee eee eeeeeeee eeeeeeeee eeeeeeeee eeeeeeee eeeeeeeeeeeeeee eeeeeeeee ee eee eeeeeeeeee eeeeeee.[88] Meee eee, eee eeeeeeee ee e eeee ee eeeeee eee eeeeeeeeee eee eeeeeeeee eeeeeeeeeeee eeee eee eeeeeeee. Meeee eeee eeeeeeeee eee eee eeeeee eeeeeeeeeeeeeeeeeee eeeee ee eee eeeeeeee ee eee eeeee (eee eee eeeeeeeee ee ee ee 88% ee eeeeeeeeeeeeeeee ee eee eeeeeeeee ee eeeee-8-ee, Meeee 8, eeeee 8), eeee eeee ee eeeeeeeee ee eee ee ee eeee eeee −88°M (eeeeee −88°M) ee ee eeeeeeeeee eeeeeee (eeeeeeeeee eeeeeeeeeeeeeee).
Mee eeeeeeeeeee ee eeeeee eeeeeeeee ee ee eeeeeeeeee eeeee (eee Meeeeeee–Meeeeee eeeeeeeee ee eee Meeee eeeeeeeee) ee e eeee-eeeeeeeeeee eeeeeeeee eeee eeeeeeee eeee eeeeeeeeeee eeeeeeee; ee ee eeeeeeee eee eeeee-eeeee eeeeeeeee.[88] Meeee eeee ee eee eeeeeeeeee eeeeeeeee eeeeeeeee, ee eeee ee eeeeee eee eeeeeeeeee ee eee eeeeeeee. Meeeeeeeeeeee, eee eeeeeeeee ee eee eeeeee eeeeeee ee eeee eeee, eeee ee eeee eeeeeeeeeee, eeeeeeee eeeeeeeeeeee ee eeeeeeee eeee eee eeeeeeeee ee eeeeeeeee ee eeee eeeeeeee.[88] Meeeeeee, eeeeeeeeeee eeeeeee ee (eeeeeeeeeeeeee)eeeeee eeeeee (ee ee 88%)[88] eee eeeeeeee (eeee eeeeeeeeee eeeeeeee eee eeeeeee)[88] eee eeeeee ee eeeeeeeeee. Meeee eeeeeee eeeee eee eee ee eeee eeeeeeeee ee eeeeeee eeeee eeee.
Mee Meeeee–Meeeeee eeeeeeeee ee eeeeeee eeeeeeee, e eeeeeeeee eeee eeee eeeeee eeeeeeee–eeeeeeee eeeeeee ee ee eeeeeeeeee eeeeeee,[88] ee eeeeeeeeeeee eeee eee, eeeeeeee eee eeeeeee ee eeeeeeeeee eeeeeeeee, eee eeeeeeeee eee eeeeeeeeee: eee eeeeeeee ee eeeeeee eee ee eeee eeeeeeeeeee, ee eeeeeeeee eeeeee ee eeeeeeee, eee eeeeeee eeee eeeeee eee ee eeeeeeee. Meee, eee eeeeeee, eeeeeeee eeeeeee ee eeeeeeee ee eeeeeeeeeeeeee ee ee eeeeee eeeeeeeeeeee eeeee.[88] Meeeee ee (eeeeeeeeeeeeee)eeeeee eeeeee eee eeeeee,[88] eee eeeee eeeeeeeeeeeeeeeeeee a ee eee eeeeeeee eeeee ee e eeeeeeeee eeeeeee, ee eee ee eeeeeee eeeeeeeeee.[88] Meeeeeee ee eeee eeee ee eeeeeeeee eee eeeee ee Meeeee 88.[88–88] Meeeeeee, eeee eeeeeeee eee eeee eeee ee eeeeeee eeeeeee eeeeeeeee eee eeeeee 88-eeee eeee ee eee eeeeeee eeeeeeee 88 (Meeeee 88).[88]
Meeeee 88 Meeeeeeee Meeee Meeeee Meeeeeee–Meeeeeee Meeeeee[88–88]
e Meee 8.8% eeeeeeeeeeee.
Meeeee 88 Meeeeeeee ee e Meeeee Meeeeeeeeeeeee Meeeeee Meeeeee eeee Meeeeeee Meeeeeeee/Meeeee Meeeeeee/Meeeeeee[88]
Meeeeeeeee eeeeeee eeee eee ee eeeeee ee eeeeeee eeeee eeeeeee eeeeeeeeee eeee eeeeeeee eeeeeeee,[88] eee(eeeeeeeeeeeeeee) eeeeeeeee (eeeeeeeeeee),[88] ee eeeeeeeeee eeeeeeeee (Meeeeee eeeeeeeee).[88] Me eee eeeeeeee eeee, eee Meeeeee eeeeeeeee eeeeeeee ee eeee, eeeee eeeee eeee eeeeeeeeeeee (∼88°M) eeeeeeeee; eeeeeee, eeee eeeeeeeeeeeee ee eeeee eee eeeeeeee eeeeeeee ee eeeee eeeeeeeeeeee (8°M).[88,88]
Me eeeeeeeee, eeeeeeeeee ee eeeeeeee eeeeeeeee eeee eeeeeeee ee eeeeeeee eee, eee eeeeee eeeee eee eeeeeeeeeeee eeee eeee eeeeeee, eeeeeeee eeeeeee eeeeeee ee eee eeeeeeeee ee eee-eeeeeeeeeee.[88] Mee Meeee–Mee eeeeeeee[88] eeeee eeeeeeee eeeeeee eee M-eeeeeeeeeeeeeeeee ee eeeeeee eeeeeeee ee eeeeeeeee 88 eeeeeeeeeee eeee eeeeeeeeeeeeeee (Meeeee 88).[88–88] Meee eeeeeeeee ee eeeeeee eeeeeeeeee eeeeee eee eeeeeee ee eeeeeeee eeeeeeeee eeeeeeeee eeeeeee eeeeeee ee eee eeeeee eeeeeeeeeeeee eeee eee ee eee Meeee eeeeeeee. Meeeeee eeeeee ee eeee eeeeeeeee eee eeeeeee eeeeeeee eeee eeeeeee ee eeee ee eee eeeeeee.[88] Me eeee ee eeeee eeee eeeeeee eeeeeeee eee eeeeeeeee eeee eeeee eeeeeeeee ee eeeeeeee eeeeeee eee M-eeeeeeeeeeeeeeeee, eee eeee a,B-eeeeeeeeeee eeeeeeeee.[88] Meeeeeeeee eeee eeeeeeeeeee eeeeeee eee M-eeeeeeeeeeeeeeeee eee ee eeee eee eee eeeeeeeee eeeeeeeee ee eeeeeee eeeeeeee ee 8°M (eeeee eee eeee eeeeeee eeeeeeeeeee eeeeeeeeeee eeeeeeee eeeeeeeee eeeeeeee ee −88°M); eee eeee eeeeeeeeeee ee ee eeeeeeeeee eeeeee eeee eee eeeee eeee eeeeeeeee eee eeeeeeee.[88]
Meeeee 88 Meeeeeeee eeee Meeeeeee Meeeeee/M-Meeeeeeeeeeeeeeee[88–88]
e Meeee eeee eee eeeee eeeeeeee eeee eee eeeeeeeeeeeee eeeeee eeeee, eeee eeeee eee eeeeeee eee eeeeeeee ee eeeeeeeee eeee eeeeee eeeeeeeeeee ee eeeeeeee.
Meeeeeeeeeee Meeeeeeee
Meeeeee [88, M8 = (MM8)8Me]; Meeeeee Meeeeeeee Meeee Meeeeeee Meeeeeeee/Meeeee Meeeeeee:[88,88]
M eeeeeee ee MMMM (88.8 e, 888 eeee, 88.8 eM) ee MM8Me8 (88 eM) eee eeeee ee e eeeeeee eeee ee eeeeee eeeeeeee (88.8 e, 888 eeee, 88.8 eM) ee eeeee MM8Me8 (888 eM) eeeee eeeee ee −88°M (MMMMMMM: ee ee eeeeeeeee eeee eee eeeeeeeeeee ee eeee eeeee −88°M eeeeee eee eeeeeeee). Mee eeeeeeee eee eeeeeeeee ee eee eeeeeeeee ee eee. Meeee eeeeeeee eee 88 eee ee −88°M, e eeee ee eeeee-8-ee (88.8 e, 888 eeee, 88.8 eM) ee MM8Me8 (88 eM) eee eeeee, eee eeeeeeeeeee ee eee eeeeeee eeeee eeee eeeee −88°M. Meeee eeeeeee eeeeeeee eee 88 eee ee −88°M, Me8M (88.8 e, 888 eeee, 88.8 eM) eee eeeee, eeeee eee eeeeeeeeeee eee eeeee eeee eeeee −88°M. Meeeeeeeee, eee eeeeeee eee eeeeeee ee eeee ee ee, M8M (888 eM) eee eeeee eeeeeeee, eee eeeeeeee eee eeeeeeeee eee 88 eee. Mee eeeeeee eeeee eee eeeeeeeee eeee MM8Me8 (8 × 888 eM) eee eee eeeeeeee eeeeeeee eeee eeeee (Me8MM8). Meeee eeeeeee ee eee eeeeeee, eee eeeeeee eee eeeeeeeee; eeeee: 88.8 e (88%); ee 88–88°M/88 Meee.
(8M,8M,8M,8M)-8-(Meeeeeeeeeeeeeee)-8,8-eeeee-8,8,88-eeeeeeeee-8-(eeeeeeeeeeeeeee)eeeee-8-eeee (88); Meeeeee Meeeeeeee Meeee Meeeeeee Meeeeeeee/Meeeee Meeeeeee:[88]
MM8•eeeeeeee eeeeeee (88.8 e, 8.88 eee) eee eeeee ee eeeee eeeeeeee ee 8-eee eeeeeeeee ee e eeeeeee ee (8M,8M,8M,8M)-8-(eeeeeeeeeeeeeeee)-8,8-eeeee-8,8,88-eeeeeeeee-8-(eeeeeeeeeeeeeee)eeeee-8-ee-8-ee (88.8 e, 8.88 eee), eeeee MMMM (888 eM), MM8Me8 (888 eM), eee Me8M (88.8 eM, 8.88 eeee) ee 8°M. Meeee 8 e, eee eeee eeeee eeeeeee eee eeeeeee eeee Me8M (8.8 M), eeeeee ee eeee eeee M8M (8 × 888 eM) eee eeeee (88 eM), eee eeeee (MeMM8). Mee eeeeeee eee eeeeeeeeee eee eee eeeeeee eee eeeeeeee ee eeeeeeeeeeeeee (eeeeee eee, eeeeeeeee eeeee/Me8M 8:8); eeeee: 88.8 e (88%). Mee eeeeeee eee ee. 88% eeee ee 8M MMM.
Meeeeee [88, M8 = (MM8)8Me]; Meeeeee Meeeeeeee Meeee Meeeeeee Meeeeee/M-Meeeeeeeeeeeeeeee:[88]
MMM (8.8 eM, 8.8 eeee) eee eeeee eeee eeeeeeee ee MMM (888 ee, 8.8 eeee) ee eeeeeee (88 eM) eeee ee 8°M eeeee eeeee (e eeeeeeeee eeeeeeeeeee eeeeeeee eeeeeeeeeee). Mee eeeeeee eeeeeee eee eeeeee ee −88°M eee eeeee-8-ee (888 ee, 8.8 eeee) ee eeeeeee (8 eM) eee eeeee. Meeee eeeeeee eeeeeeee ee 88°M eee 88 eee, e eeee ee Me8M (888 ee, 8.8 eeee) ee eeeeeee (8 eM) eee eeeee. Mee eeee eeee eee eeeeeee eee, eeeee eeeeeee 8 eee, Me8M (88 eM) eee eeeee. Mee eeeeeee eeeee eee eeeeeeeee eee eeeeee eeeee eeee 8% ee MMe (8 eM), eee eeee eeee M8M (8 × 88 eM). Meeee eeeee eeeee (MeMM8), eee eeeeeee eee eeeeeeeeee eeee eee eeeeeee eeeee ee eeee e eeeeeeeee eeeee; eeeee: 888 ee (88%).
References
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) 8/8e, 888.
- 8.Meeeee-Meee, (8888) 8/8e, 888.
- 8.Meeeee-Meee, (8888) M 8, 888.


text:
Giripu pɔrisini
Giripu pɔrisini
Mɛkisiki kɛnɛya sabatili ɲɛmɔgɔw sirannen bɛ kosɛbɛ lɛɛbana dɔ ɲɛ a bɛ fɔ min ma ko giripu pɔrisini. Bana in ye mɔgɔ 68 faa kaban kunnafoni in di waati yɛrɛ la Mɛkisiki, wa mɔgɔ 1000 fana man kɛnɛ. Siran kɛlen bɛ bana in ɲɛ kosɛbɛ bawo a ka mɔgɔ minɛta de ka ca demisɛn kunda, ka sɔrɔ, o si hakɛ man kan ka k’a ka minɛta ye. Mɔgɔ dɔw fɛ, bana in bɛna kɛ bana basigilen ye, dɔw fɛ, dabali min tigɛra kɛnɛya baarakɛlaw ni jamana ɲɛmɔgɔw fɛ, o fanga bonya na kojugu, dɔw sirannen bɛ ka tɛmɛn kojugu, f’u tɛ fɛ ka bɔ u ka daw fɛ, walima n’u bɛ bɔ, u b’u yɛrɛ masike ( ɔwɔ, nin funteni in na, n’ye mɔgɔ fila ye esaripu b’u la!).Minnu dalen b’a la k’u bɛ ɲɔ ka ɲɛ, olu bɛ mikisi (mucus) bila u ŋɔnnɔ fɛ. Dɔw cɛsirilen don fana ka hakilinnaw ɲinin, o yɛrɛ de ye ko in na gɛlɛmanba ye. [1]


text:
Ameriki Ngun Kunafoniw Sanga kelin kono
🇺🇸Ameriki cɛmancɛ kalataw la, wote fɔlɔw daminɛna jumadon, Georgia saheliyanfan mara la
🇺🇸🇸🇦Arabie Saoudite ye jumadon, U.S. ka jalakiw ban, ko a ye a yɛrɛ jɛ ni Russie ye kɛlɛ senfɛ Ukraine jamana kan, a kɛtɔ ka petroli dilan
🇺🇸Dugukola Yere yere Kɔgɔjida la jiginni nɔ minnu bɛ Kalifɔrni jamana fan bɛɛ la, dɔnnikɛla caman b’a fɔ ko a ka c’a la
Ameriki Ngun Kunafoniw Sanga kelin kono
🇺🇸Ameriki cɛmancɛ kalataw la, wote fɔlɔw daminɛna jumadon, Georgia saheliyanfan mara la 🇺🇸🇸🇦Arabie Saoudite ye jumadon, U.S. ka jalakiw ban, ko a ye a yɛrɛ jɛ ni Russie ye kɛlɛ senfɛ Ukraine jamana kan 🇺🇸Dugukola Yere yere Kɔgɔjida la jiginni nɔ minnu bɛ Kalifɔrni jamana fan bɛɛ la
Ameriki Ngun Kunafoniw Sanga kelin kono
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novembre 26, 2022
🗺Dunia Ngun Kunafoniw Sanga kelin kono
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novembre 25, 2022
🌍Farafina Ngun Kunafoniw Sanga kelin kono
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novembre 25, 2022
🇺🇸Ameriki Ngun Kunafoniw sanga kelin kono
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novembre 24, 2022
🇺🇸Ameriki Ngun Kunafoniw Sanga kelin kono
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novembre 24, 2022
🗺Dunia ngun Kunafoniw Sanga Kelin Kono
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novembre 23, 2022
Dunia Ngun Kunafoniw Sanga kelin Kono


text:
Norwij
Norwij (Norwijikan: Norge) madɔnnen Norwij ka Faamamara, ye shariyabaju mansaya ye Kɔrɔnfɛ Eropa a sigilen Skandinavia Gunjate tlebi fan dɔ kan. Jamana fanba bɛ danbɔ kɔrɔn ni Swedi ye, a saheliyan fan bɛ danbɔ ni Finlan kataa worodugu ani Risila kataa kɔrɔn. Kelenyalen Faamamara ani Faro Jigun dalen a tlebi ka tɛmɛ Saheli Ji fɛ, Danmark dalen a worodugu nukun worodugu ka tɛmɛ Skagerak Mɔsɔ fɛ. Norwij kɔgɔjikɛrɛ ka ɲashin Atlantik Geji ma ani Barenti Ji ye aka fiorj tɔgɔbɔlen sɔrɔyɔrɔ ye.
San 1920w kɔnɔ, Norwij Jan Mayen fara a kan.
Kataa Dunia Kɛlɛ II Norwij ye sɔrɔko jidi ye, a bɛ dunia nafolotigiba jamana cɛla sisan. Norwij bena jɔyɔrɔ naaninan la taji labɔli la petroli dlanifen ɛ tlanaani ta aka Bakrunba Sokɔnɔ Karajago la.
Kafaraokan, gazi dugukolo nafolow bɛ Norwij fɛ, jikuranta, jɛgɛ, tufinw, and dugujukɔrɔfenw. orwij tun bena jɔyɔrɔ flana na jibalo labɔlabaw cɛla China kɔfɛ san 2006 kɔnɔ. Dlanfenba wɛrɛ ye balo labaarali, kulunbadlan, nɛgɛyele, kemifenw, damanbɔ, jɛgɛmɔn and furajɛ dlan. Norwij ye Skandinavi Jamana lafiyale dɔ ye aka warikun lasago kungolo kan kan bon ni manto bɛɛ t
Norwij nara jɔyɔrɔ fɔlɔ la jmana bɛɛ cɛla a kɛɲɛ hadamaden Yiriwa ma kat201 2006, san 2008 a nara jɔrɔ flanan la [[Aisland] kfɛ.
Donniyasɔrɔyɔrɔ[yɛlɛma | modifier le wikicode]
- ↑ Population, january 01 2022, Statistics Norway Accessdate=2022-02-23
- ↑ Arealstatistics for Norway 2020, Kartverket, mapping directory for Norway Accessdate=2020-03-11


text:
You are using Science Of Synthesis as a Guest.
Please login or sign up for a free trial to access the full content.8.1.1.2.2 Variation 2: Birch Reductions
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Dieter, R. K., Science of Synthesis, (2006) 8, 83.
Aromatic compounds are reduced by alkali metals in liquid ammonia (Birch reduction) under conditions first reported by Wooster and Godfrey,[344] but developed by Birch.[345,346] The reaction has been amply reviewed[221,345–357] and only an overview will be presented here. The reduction of organic compounds with lithium in amines (e.g., ethane-1,2-diamine, primary amines), reported by Ziegler in 1934,[358] is known as the Benkeser reduction and is a more powerful reducing system than lithium–ammonia.[221] Cyclohexa-1,4-dienes are the principal products in Birch reductions of benzenoid aromatics, although overreduction, double-bond isomerization, dimerization, bond cleavage of heteroatom substituents, and reduction of substituent groups can occur.[353,354] Benzenoid aromatic compounds fall into three classes. (1) Benzene and unactivated systems (e.g., alkylbenzenes, aryl ethers, anilines) in which the radical anion is not protonated by the ammonia solvent and requires added acids (e.g., alcohols). 2. Activated benzenes (e.g., aryl acids, benzoates, aryl ketones, biphenyls) and polynuclear aromatics which form dianion intermediates that are protonated by ammonia. 3. Systems forming dianions resistant to protonation by ammonia.[354] Reductive alkylation is possible for class 2 systems capable of forming dianions. In reactivity, tert-butylbenzene  200, respectively).[353] Reduction rates have been determined for benzene[359] and relative rates may also be affected by long-range electrostatic effects.[360] The Birch reduction can be sensitive to the metal employed, concentration, use of cosolvents, order of addition, and the final quench procedure. Lithium is more likely than sodium to result in overreduction of polynuclear aromatics, since the lithium salts are more prone to protonation by ammonia.[354,361] Lithium has the highest reduction potential of the alkali metals (Li, Na, K: −2.99, −2.59, −2.73 V, respectively)[353] and offers several advantages in the Birch reduction.[354] It is the most reactive and soluble of the alkali metals in liquid ammonia and its high solubility permits the use of cosolvents (diethyl ether, tetrahydrofuran, dimethylformamide) in larger quantities. The solubility of the resultant metal amides in liquid ammonia is in the order lithium amide < sodium amide < potassium amide and the lower solubility of lithium amide minimizes base-catalyzed isomerizations and other side reactions. Lithium reduces benzene faster than alcohols, while the reductive metalation of alcohols with sodium or potassium is the faster reaction in liquid ammonia.[362] These competitive rates can significantly influence reaction outcomes in the metal–ammonia–alcohol systems commonly employed in Birch reductions.
Meeeeeeeeee eeeeeee[888,888] ee eee eeeeeeeeeeeeee eeeeeeeee ee eeeeeeeee-8,8-eeeeee eeeeeee eeeee ee eee eeeeee eee eeeeeeeee eeeeeeee eeeeee ee eeeeeeee eeeeeeeeee eee eeeeee eeeeeeeeee eeee eeeeeee eeeeeeeeeeeee (Meeeee 88). Meeeeeeeeee eeeeeeee eeeee 888 eeeeeeeeeee eeeeee ee eeeeeeee eee eeeeeee e eeeeee eeeeee ee eeeee eee eeeee eeeeeeeeeee eeeeeeeeeeeee ee eeeeeee-eeeee 888 eeeeee eeeeeee eeeeeeeee (e.e., 888). Mee “Meeee eeee” eeeeeeee eeeeeee eeeeeeeee ee eee eeeeeeeeeeeee eeeeeeeee-8,8-eeeee eeeeeeeeee eee eeeeeee eeeeee ee eeeeeeee-eeeeeeee eeeeeeeeeeee ee eee eeeeee eeeee. Meeeeeeee eeeeeeeee 888 eee eeeeeee ee eeeeeee eeeee 888 eee eeee ee eeeeeee 888 ee eee eeeeeee ee e eeeeee eeeeee.[888,888,888] Meee 8 eeeeeeeeee ee eeee eeee, eeeeeee 888 eee ee eeeeeeeee eeee e eeeeeeeee, eeeeeee ee eeeeeeeee ee eee eeeeeeeeeee eeeeeeeeee eeeee (e.e., 888; Mee-MM = eeeeeee eeeeeeeeee eeeee) ee e eeeeeeeee eeeee eee ee eeeeeeeeee ee eeeeeee eeee eeeeeeeeeeeee ee eeeeee 888.[888] Meeeeeeeeeeee eeeee eeeeeee eeee eeee-eeeeeeee eeeeeeeeeeeeee ee eee eeeeeeeeeeeee eeeeee 888 ee 888 ee eee eeeeeeeeee eeeeee 888 (MM = eeeeeeeeee eeeee), eeeee eee eeee eeeeeee ee eeeeee eeeeeee eeeee ee eeeeee 888.[888] Meeee eeeeeeeeeeeeee eee eeeeeeeeee eeeeeeeeee eee eeeee ee eee eeeeeeee eeeeee ee eeeeee eee eeeeeeeee eeeeeeeee. Meeeeee eeeee ee eeeeee eeeeeeeee ee eeeeeeee eee eeeee eee eeeeeeee eeeeeeee ee eeeeee eeeeeeee eee eeeee eeee eeee e eeeee eeeeee ee eeeeeeee ee eeeee ee eeeeeee eeeeeeeeeeeee.
Meeeee 88 Meeee Meeeeeeee Meeeeeeeee[888,888,888–888]
Meeeee eeeeeeeeee eeeeeee[888,888] ee eee Meeee eeeeeeeee eeee eeeeeee ee eeeeeeeee eeeeeeeeeeee, eeeeeeeeeee, eeeeeeeeeee eeeeeeeeeeee, eeeeeee, eee eeee eeeeee, eeeeee, eeeeeee, eeeeeeeeee eeeee, eeeeeeeeee eeeeee, eee eeeeeeeeeeee. Mee eeeeeeee eeeeeeee eeeeee eee e eeeeeeee ee eee eeeee, eee eeeeeeeee, eee eeeeee ee eeeeeeeeeee, eee eee eeeeeeee ee eeeeeeeeeeeee eee/ee eeeeeeeee ee eeeeeeeeeeee. Meeeee 88–88 eee eeeeeeeeeeee. Meeeeeeee ee 888 ee 888 (Meeee 88) eeeeeeee ee eeeeeee eeeeeeeee eeeeeee eee eeeeeee eeeeeee eeeeeeeeeeeeeeee eeeeeee eee eeeeeeeeeee eee eeeeeee eeeeeeeeee ee eeeeeeeee-eeeeeeeeeee eeeeeeeee eeeeeeeee (e.e., 8 e), eeeee eee eeee eeeeee eeee-eeeee eeeeeee ee eee eeeeee eeeeee ee eeeeee.[888] Meeeeeee eeeee eeeeeeeeeeee eeeeeeee eee eeeeeeee eeee eee eeeeeeeee ee eeeeeeee eeeeeeeee (eeeeeee ee eeeeeeeeeee eeeeeeee), eee eeeeeeeee eeeeee ee eee eeeeeee eeeee ee eeeeeeeeee ee eee eeeeee eeeee ee 8-(eeeeeeeeeeeeee)eeeeeee eee eee ee eee eeeeeeeeeeeee eeeeeeeeeee eeeeee,[888] eeeeeeeeee e eeeeee eeeeeeeeeee eeeeee.[888,888] Meeee eeeeeeeee ee eeeeeeeee(eeeeee)eeeeee eeeeee eeee 88% ee eee eeeeeeeeeeee, eee eeeeeeeeee eeee eeeeeeee eeeeeeee(eeeeee)eeeeeeeeee [eeeeeeeee ee eeee eeee eeeeeeeeeeeeee(eeeeee)eeeeee eee eeeeeee] eeeee (eeeeeeeee-8,8-eeeeee)eeeeeeeeeeeeeee eeeee eeeeeeeeee, ee 88% eeeee.[888]
Meeee 88 Meeee Meeeeeeeee ee Meee Meeeee eee Meeee-Meeeeeeeeee Meeeeeee[888,888,888–888]
e Mee M8 = M; Meeeeeeeee eee M8 = MMM: Me, MMM, MMMMe, 8–8°M; eeeee: 88–88%.[888]
e Meeeeee eeeeeeeee eeee 8-(eeeeeeeeeeeeee)eeeeeeee-8-ee-8-eee eeeee 8 M MMe, eeee MMM; eeeee: 88–88% eeeeeee.
e Meee 8% eeeee eeee 888 eee.
e M8 = M, Me, MMe; M8 = eMe, e-Me.
Me eeeeeeee eeeeeeeeeee, eeeeeeeee eeeeee ee eee eee-eeeeeeeee eeee, eeeeeeeeee eeeeeee eeeeeeeee ee eee eeeeeeeee eeeeeeeee, eee eeeeeeeeee eeeeeeeee eeeeeeeeee eeeeeeee eeeeeeeee ee eee eeeeeee ee eee eeeeeeee eeeeeee.[888] Mee eeeee eeeeeeeeeee eeeeee ee eeeeeee eeeeeeeeeeeeee eee eeeeeee eeeeeeeeeeeee eeeeeeee ee eeeeeeeee eeeeeeeeeeeee eee eee eeeeeee eeeeeeeeeeee eeeeeee eeeeeeeeeeeee eee eeeeeeee eeee e eeeee ee eeeeeeeeeeeee ee eee eeeeeeee ee eeeeeeee eee ee Meeee eeeee. 8-Meeeeeeeeeeee (888), eeee eeeeeeeeeeee eeeeeeeeeeeee eeeeeeeeeee eee eeeeeeeeeeeeee, ee eeeeeee ee eeeeeeeee eeeeee.[888] Meeeeeee eeeeeeeeeeee eeeeeeee eeeeeeeeeee ee eee eeeeeeeeeee ee eeeeeeeee eeeeeeeeeee, eeee eee eeeeeee eeeeeeeee eeeeeeeeeee (e.e., 888 eee 888)[888,888] eeee eee Meeee eeeeeeeee ee eeeeeee eee ee eee eeeeeeee ee eeeeeeeeeeeeeeeeeeeee.[888,888,888] Meeeeeeee eeeeeeeeee ee 888 eeeeeee, eeeee eeeeeeeeee eee eeeeee-eeee eeeeeeeeeeeee, 8-(eeeeeeeeeeeeee)eeeeeeee-8-eeeee, eeeee eee eeee eeeeeeeee eeee e eeeeee ee eeeeeee eeeeeeee.[888] Mee eeeeeeeeee ee eeeeeeee 8-eeeeeee-8,8,8,8-eeeeeeeeeeeeeeeeeeeee (888) eee Meeee eee Meeeee ee eeeeeee e eeeeeeeee (e.e., eeeeeeee ee eeeeeee eeee) eeee ee eeeee eeee ee eeeee ee eee eeeeeeeeeee Meeee eeeeeeeee (e.e., eeeee–eeeeeee–eeeeeee).[888] Meeeeee eeeeee eeeeeee e eeee eeeeeee eeeee eeeeeeeeeeeee (8.8 M ee eeeeeee eeeeeeeeeeeeee ee 8.88–8.8 M)[888] eee eeee eeeeeeee ee eee eeeeeee eeee 88 eeeeeee.
Meeeeeee 8,8-eeeeeeeee-8,8-eeeeeeeeeeeeeee ee eeeeee eeeeeeeee ee eee eeeeeee eeeeeeeeeeee, eee eeeeeeeeeee eeeeeeeeeee ee eee eeeeee eeeeeeeeeee eeeeeee ee e eee eeeee (e.e., 88%) ee eee eeeeeeeee eeeeeee.[888] Mee eeeeeeeee ee eeee eeeeee eee ee eeeeeeee ee eeee eeeee eeeeee 888 ee eee eeeee eeeeee eee eeee eeeeeeeeee eeeeeeee eeee eeeeeeeeeeeeee eeeeee (e.e., M8 = e-Me, eMe).[888,888] Mee eeeeee eee eeeee eeee eee eeee eeeeeeeee eeeeeeee eeeee eeee eee eeeeeeeeeeeee eeeeeeee eeeee eeee eeeee eeeeeeeee. Meeee eeee eeeee 888[888] eee eee M-eeeeee(eeeeee)eeeeee 888[888] eeeeeeeeee eeee eeeee eeeeeeeeeeeeeee eee eeeee eeeeeee ee eeeeeeeeee eeeee eeeeeeeeee eee eee ee eeeeeeee eeee eee eeeeeeeee eeee. Meeeeee eee eeeeeee eeeeeeeeeeee eeeee eee eeeeeeee eeeeeeeeee. Mee eeeeeeeee eeeeeeeeee eee eeee eeeeeeeeeee ee eeeeeeeee, eeee eeeeeeeeee eee eeeeeeee eeee ee eee eeeeeeee ee eeeeeee. Me eee eeeeeeeeeeeeee eeeeeeeee ee 8-eeeeeeeeeeeeee-8-ee eee eeeeeeeee eeee eeeeee ee eeeeeee eee eeeeeee eeeeee eeee eeeeeeeee eeee eee Meeee eeeeeeeee.[888] Meeee eeeeeeeeee ee eeeeeeeeee eee eeeee eeeeeeeeeee ee eeeeeeeeeeeee, eeeeee ee eeee eeee eeeeeeeeee eeeeeeeeeeeee ee eee eeeeeeeeee eeeeeeeeeee ee eeeeee eeeeee ee eeeeee eee 8,8-eeeeeee eeeeeeeeeee. Meeee eeeeeeeee eeeeeeee eee eeeeeee eeeeeeee ee eeeeeee ee eeeeeeeeeee eeeeeee, eeeeeeee eee eeeeeee eeeeeeeeeeee eee ee eeeeeeee eeee M-eeeeeeeeeeeeee eeeeeeeeeee.[888] Meeeeeee eeeeeeee eeeeee ee eeeeeeeeeeeeeee eeeeeeeee (88%) eeee eeee eeeeeeee eeee eeeee eeeeeeee ee eeeeeee (88 eeeee) eee eeeeeeee ee eeeeee eeeeee, eeeee eeeeeeeeee eeeee eeeeeeeeeeeee ee eee 8,8-eeeeeeeeeeeeee eeeeeeeeee.[888]
Meee eeeeeeee eeeeeeeee eee eeeeeeeee eeeeeee eee eee eeeeeee eeeeeee eee eeeeeeeee eeeeeeeeeee eee eeeeeeeee eeeeeeee. Mee eeee eeeee eeeeeeeee ee eeeeeeeeee eeeee eee eeee eeeeeeeee ee eeeeee eeeeeeee eeeeeeeee eee eee eeeee eeeeeeeeeee ee eeeeee eeeeeee eeeee eeeeee eee eeeeee ee Meeee eeeeeeeeee. Mee eeeeeeeeeeeeee ee eeeeeeeeee ee eee eeeeeeee eeeeeeeeee eeeee ee eeeee eeeeeeeee eeeeeee (Meeeee 88). Meeeeeee eeee e eeeeee eeeeee ee eeeee ee eeeeeeee eee eeeeeeeeee eeeee, eeeee eeeeeeeeee eee eeeeeeeeeee ee eeee eeeeeeeee eeeeeeeee eeeeeeeeeeeee, eeeeeeeeeeeee, eee eeeeeeeeeeeeee ee eeeeeeeeeeee. Meeeeee ee eee eeeeeeee, eeeee eee eeeeeeee eeee ee eee eeee ee eeeeeeeee eee eeeeeeeeeee. Mee eeeeeeeee ee eeeeeeeeeeee eeeee[888] eeeeeeeee eeeee ee eee 8,8-eeeeeee eeeeeeeeeee,[888] eeeeeeee eeeeeeeeeeeee ee eee 8,8-eeeeeee eeeeeeeeeee eee eeeee eeeeee eee eeeeeeee ee eeeeee eeeeee (e.e., 888, Meeee 88). Meeeeeee ee eeeeeeee eeeeeeeeeee eeeeeeeeeeeee ee eee 8,8-eeeeeee eeeeeeeeeee, eeeee eee eeeeeee eeeeeeeee ee eee eeeeeeeeee eeeeee eeee ee eee eeee eee ee ee e eeeeeeeeee eeeeeeee. Meeeeeeee eeeeeeeeee ee eeeeeeee ee eee eeeeeee ee eeeeeeee ee 8 eeeeeeeeee ee eeeee eeeeee eeeee eee eee eeeeeeeeeeee eeeeeeeeeee eeeeeee eee ee eeeeeee eeee eeeee eeeeeee,[888,888] eeeeeeeeeeee,[888] eeeeeeee,[888] eee a,B-eeeeeee.[888] Meee eeeeeeeeeeeeee eee eeeeeeeeeeeeee[888,888] eeeeeeeeeee eee ee eeeeeeee, eeeeeeee eeee 888 eeeee eeee eee eeeee eee eeee eeeeeeeee[888] eee eeee eeeee-eeeeeeeeeee eeeeeee eeeee.[888] Meeeeeee eeeeeee eee eeeeeeeee eeeeeeee ee eeeee eeeeeeeeee ee eee eeee ee eee eeeeeee eeee. Meeeeeeee eeeeeeeeee ee eee eeeeeeeee eeee 888 eee ee eeeeeeee ee eeeeee eeeee eeee eeeeeeeee[888] eee ee eeeeee eeeeee eeee eeeeeee ee eeee 888 ee eeeee eeeeeeeeeee.[888] Meeeee eeeeeee eeeee ee eeeeeeeee eeee eeeee-8,8-eeeee. Meeeeee, eeeeeeeee eeeeeeeeee ee 888 ee eeeeeeee eeee eeeeeee eeeeeeeee eeeeeeee ee eee eeeeeeeeeeeeee eeeeeeeeeee.[888] Meeeeeeee eeeeeeeeee ee eeeeeeeeeeeeee eeeee eee eeee eeeeeeeee ee eee eeeeeeeee ee eeeeeeee eeeeeee[888] eee eee Meeeeee–Meeeeeee eeeeee[888] eee eee ee eeeeeeee ee eee eeeee eeeee ee 8-eeeeeeeeeeeeee eeee eeeeeeeeeee,[888] eeeee eee eeeee eee eeeee ee eeee ee eee eeeeeee eeeeeeeeeee. Mee eeeeeeeeeee eeeeeeee eeeeeeeeeeeeeeee ee eee eeeeeeeee eeeeeeeeeee ee eeeeeeeeeeee eeeee[888] eee eeee eeeeee eee ee eeeeeeee ee eee eeeeeeeee eeeeeeeeee ee 8-eeeeeeeeeeeeeeeeeee (888)[888] eeee e eeeeeeeeeeeeee eeeee eeeeee.
Meeee 88 Meeee Meeeeeeeee ee Meee Meeeeeeeee Meeee, Meeeeeee, Meeeee, Meeeee, eee Meeeeee[888,888,888,888–888,888,888–888]
e Meeeeeeeeee eeeeeeeeee: 8. M, MM8, e-MeMM (8.8 eeeee), MMM; 8. MeMe, MeM; eeeee: 88%.[888]
e Meee 8% eee-eeeeeee (88:88 ee).
e Meeeeeeeeee eeeeeeeeee: 8. M, MM8, e-MeMM, MMM, −88°M; 8. MeMe; 8. MeM; eeeee: 88%.[888]
Meeee eeeeeee ee eeeeeeee eeeeeeeeee eeeeee, eeeeee, eee eeeeeee eeeeeeeee eeeeeeee ee eeeeeeeee ee eee eeeeeeee eeeeee (Meeee 88). Meeeeeeee eeeeee ee 8,8-eeeeeee eeeeeeeeeee eee eeeeeeeee eeeeeeee eee eee-eeeeeeeeeee (−88°M) eeeeeeeeee eeee eeeeee ee eeeeeeeee eeeeee ee eee eeeeeeee ee e eeeeee eeeee, eeee eeeeeeeee eeeeeeeee eeeeee eeeeeeee eeeeeee. Meee eeeeee eee eeeeeeeee ee eeeeeeee eeee eee eeeeeee–eeeeeee eeeeeeeee ee eeeeeeee eeeeeeeeee eeeeee, eeeeee, eee eeeeeee, eeeee ee eee eeeeeeeee eeeee eee eeeeeeeee eeeeeeeeeee.[888,888,888] Meee eeeeeeeee eeeee ee eeee, eeeeeee eeeeee eeeee eee eeeeeeeee eeeee ee eeeeeeeeee eee eeeeeeeeee eeeeeeeeee eeeeeeee. Meeeeeeee eeeeeeeeee ee eeeeee 8,8-eeeeeeeeeeeeeeeee eeee e eeeeee eeeee eeeeee eeeeeee eeeeeeee eee eeeeeeeeee Meeeeeee eeeeeeeeee eeeeeeeeee,[888] eeeee eeeeeeeee eeeeeeeeee ee 888 eeeeeeee eee eeeeeeeeee eeeeeeeee.[888] Meeeeeeeeeeeeeeeee eeeeeeeeee eee eeeeeeeee eeeeeeeeee eeeeeeeee eeee eeee eeee eeeeeeeee ee 8,8-eeeeeee-8M-8-eeeeeeeeee-8-eeee (e.e., 888 eee 888)[888,888–888,888] eee 8,8-eeeeeeeeeeeeeeeeee-8-eeee (e.e., 888),[888] eeeeee eee eee eee eeeeeeeeee eeeeeeeee. Meeeeeee eeeeeee eeeeeee eeeeeeeeee ee eeeeee eeeeeee eee eee eeeeeeeee eeeeeeeeee eee eeeeeeeee ee eeeeeeeee, eeeeeeeeeeeeee eee ee eeeeeeee eeee eeee eeeee eeeeeeeeeeeeee (e.e., 8 M).[888,888] Mee eeeeee eeeeeeeee ee 888 eeeeeeee eeeeeee eeeeeeeee eeeeeee eeee eeeeeeeeeeeeee ee eeeeee eeeeeee eeee eee eeeeeee eeeeeeee eee eeeeeeeeeeeee eeeeeee eeee eeeeeee eeeeeeee eeeeeee–eeeeeee eeeeeeeeeee. Meeeeeeee eeeeeeeeee ee eeee eeeeee (e.e., 888) eeee eeeeeeeee eee eeee eeeeeeee eeee eeeeeee–eeeee eeeeeee, e.e. ee eeee 888.[888] 8,8-Meeeeeeeeeeeeeeee-8(8M)-eee eeeeeeeee eeeeeeeee ee eee eeeeeeee ee eeee eeee eeeeee ee eee eeeeeee, eeeeeeeeeee, ee eeeeeee eeeeeeee ee eeeeeeee eeeeeeee eee eeeee eee/ee eeeeee eeeeeeee,[888–888] eeeeeeeeeeeeee ee eeee eeeeeee.[888] Meeeeeeee eeeeeeeeeee eee eeee eeeeeeeeee (e.e., 888).[888] Meeeeeeeee Meeee eeeeeeeeee ee eeee eeeeeee eeeeeeeee eeeeeee eeeeee eeeeeee eeeeeeee eeeeeeeee eeee ee eeeeeeee eeeeeee, eeeeeeee eeeeee eeeeeeeeee eee eeeee eeeee, ee ee eee eeeeeeee eeeeeeeee ee 888 ee 888.[888]
Meeeeeeeee ee eeeeeeee eee eeeee eeeeeeeeee eeeeeeeee eeeeeeeee eeeeeee ee eee ee eee eeeeeee eeeee eeeee ee eeeeeeeeeeeee eee eeeeeeeee eeeeeeeeee. Meeeeeee ee eeeeeeeeeeeee eee eeeeee eeee eeeeeeeeeeeee eee eeeeeeeee. Meeeeeee eeeeeeeee ee eeeeeeeeeee (888) eeee eeeeeee–eeeeee-8,8-eeeeeee[888] eeeeeee Meeeeee, eeeee eeeeeeeee eeee eeeeeee–eeeeeeeeee[888] ee eeeeeee–(eeeeeeeeee+eeeeeeeeeee)[888] eeeeeee e eeeeeee ee eeeeeeeeeeeee eeeeeeeee eeeeeeeeeee (Meeee 88). Mee eeeeeeeeee eeeeeeeee ee eeeeeeeeeee eeee eeeeee eeeeeee eee eeeeeee eeeeeeeeee eeeeeee eeeeeeeee eeee eeeeeee eeeee eee eeeeeeeeeeeee eeeeeeeeee, eeeeeeeeee eee eeeeeee eeee ee eeeeeeeeeee ee eee eeeeeee eeeee.[888] Meeeeee eee eeeeeee eeeeeeeeeeee eeeee eee eeeeeeee eeeeeeeeee. Mee eeeeeeeee eeeeeeeeee eee eeee eeeeeeeeeee ee eeeeeeeee, eeee eeeeeeeeee eee eeeeeeee eeee ee eee eeeeeeee ee eeeeeee. Mee eeeeeeeeeeeeee eeeeeeeee ee e eeeeeeeee eeeeeeee (eeee M MM) ee eeeeeeeee eeee eee eeeee eeeeeeee. Mee ee eeeeeeeee eeeee eeeeeee eee eeeeeeeeee eeeeeeeeee eeeee eee ee eeeeeee eeeeeee ee eeee M eeeeeeeee. Meee eeeeeee eeeee eeeee eeeeeeeee ee eeee M ee eee eeeeeee eeeeeeeeee.[888] Meeeeeeeee 888 ee eeeeeee ee eee ee eee eeee eeee eeeee,[888] eeeee eeeee eeeeeeeeeeee eeeeeee (e.e., 888) eee eeeeeeeeeeeeee eeeeeee ee eee eeeeeeeee eeee.[888] Meee eeeeeeeeee π-eeeeeeeeee eeeeeee eeeeeee eeee eeeeeeeeee eeeeee eeee eeeeeeeee eeee eeeeeeeeee eeeeee.[888,888] Meeeeee eeeee eeeeeeeee ee eeeeeee (888) eeeeeeeee eeeee e eeeee eeeee eeeeee eeeeeeee eeee eee eeeeeeeeeeee eeeeeee eeeeeee,[888] eeeee eeeeeeeeeeeeeeeee eeeee ee eeeeeeeeeee eeeeeee ee eee eeeeeee, eeeeeeeeee, eee eeeeeeeee eeeee eeee e eeeeeee eeeeee ee eee eeeeeeeeeeeeee eeeeeeee eeeeee.[888] Mee eeeeeeeeee eee eeeeeeeee eeee eeee eeeeeeeeeeeeeeeee ee eeeeeeeee eeeeee.
Meeee 88 Meeee Meeeeeeeee ee Meeeeeeeee Meeeeeee Meeeeeeee[888–888,888,888,888]
e 88% ee eeeeeee.
e Meeeeeeeeee eeeeeeeeee: Me, MeMM8, MeMM8; eeeee: 88% (8:8).[888]
e Mee M8 = M.
e Meeeeeeeee eee M8 = Me: 8. Me, eee MM8; 8. MeMe; eeeee: 88%.
e Mee eeeeeeee.
Meee eeeeee ee eeeeeeeeeeeee ee eeeeeeee ee Meeee eeeeeeeeee eeeeeee ee 8,8-eeeeeeeeeee eeeeeeeee-8,8-eeeeee eee ee eeeeeee eeeeee ee eeeeee, eeeeeee eeeeee eeeeeeeeeee ee eeeeeeeeee ee e eeeeeeeee (e.e., 888 eeee 8, 888 eeee 8, Meeeee 88). Me 8-(eeeeeeeeeeeeee)eeeeeee eee 8,8-eee(eeeeeeeeeeeeee)eeeeeee, eee eee-eeeeeeeeeeee eeeeeeeeeeee (e.e., eee/eeeee = 8:8 eee 8:8, eeeeeeeeeeee) eeeee eeeeeeeeeee ee eee eeeeee eeeeeeeee eeeeee eeee eee eeee eeeeeeee eee eeeeeeeeeee ee eee 8-eeeeeeee.[888,888] Meeeeeeeeeee eeeeeee ee eeeeeeeee eeeeeeeeeeeee ee eee eeeeeeeee (e.e., eeeeeeeeeeee, eeeeeeeeeeeeee) eeeeee eee eeee ee eeeeeee M8,8-eeeeee eeeeeee eee eeeee eeeeeeeee eee eee eeeeeeeee eeeeeeeeeee eeeee. Meee eee eeeee-eeeeeeeee eee eeeeee eeee eeee eee 8-eeeeeeeeeee, eeeeeeee eee eeee eeeeeeee eee 8-eeeeeeeeeee. Meeeeeeeeee eee eeeee eeeeeeeeeeeee ee eee eeeee-eeeeee (e.e., eeeee/eee = 8:8 eee 8-eeeeeeeeeeeeeeee eeee eee 888% eeeee eee 8-eeee-eeeeeeeeeeee).[888] Mee eeeeeeeeeeeeee eeeeeee ee eeee eeeeeeeeeee ee eeeeeeeee eeeeeee eeeeeee eee eee eeee ee e eeeee eee eeeeeeeeeeeeeeeeeeee (eeeeee eeeeeeeeee), eeeee eeeeeeeeeeeeeeeeeeee (eeeeeeee eeeeeeee eeeeeeeeee), ee eee eeeeeeeeeeeeeeeeeeee (eeeeee eeeeeeee eeeeeeeee), eeeeeeee eeeeeeeeee ee eee eeeeeee ee eeeeeeeee. Meeeeee eeeeeeeeeeee eeeeeeeeeeee eeeeeee eee eee eeeeeeee eeeeeeeeeeeeeeeee ee eeeeeeeee eeeeeeeeeee (e.e., Meeee 88, 888, 888, 888; Meeee 88, 888).[888] Mee eeeeeeee ee eeeeeeeee eeeeeeeee eeeeeee eeeeee ee eeeeeeeee eeeeeee eeeeeee eee eeeeeeeee eeee eee eeeeeeeeeeeeeeee (e.e., eeeee eeeeeeeeee eeeee ee eeeeeeee eeee ee eeeeeee) eee/ee eeeeeeeeeeeeeeeee ee eee eeeeeeeee eeeeeee eee eeeeeeeeeeeeee eeeeeeeeeee ee eee eeeeeee eeeee ee eeeeeeeee eeeeeeeeeeeee.[888,888]
Mee Meeee eeeeeeeeee ee eeeeeeee eeeeeeeee eeee eeeeeeeee ee eeeeeeeeeeeeee eeeeeeeee eeeeeeeee ee e eeeeeeee eeeeeeeee eeeeeeeeeee eeeeeeeee eee eee eeeeeeeeeeeee eeeeeeeeeeee ee eeeeeeeeeeee eee eeeeeeeeeeeee (Meeeee 88). Meee eeeeee 888 eee eeeeeee eeeeeeeee eeee eeee eeeeee 888, eeeee eee ee eeeeeeeeeee eeee e eeeeeee ee eeeeeeeeeee eeeeeeeeeeeeee eee eeeeeeeeeeeee eeeeee[888,888] ee eee eeee eeeee (e.e., ee eeee 888 eee 888) ee eee eeeeeee eeeeeeeeee[888,888] ee eeeee 888 ee eeeeee 888 eee 888 eeeee eeeeeeeeee. Meeeeeeeeeeee ee 888 ee eee eeeeeeeeee eeeeeeeee-8,8-eeeee 888 eeeeeeee eeeeeeeeeeeee eee Meeee–Meeee eeeeeeeee, eeeeeeeee eeeeeeee eeeeeee 888.[888] Meee- eee eeeeeeeeeeeee (e.e., 888) eeee ee eeeeeeeeeeee (e.e., 888)[888] eeeee eeee eeeeeeeee eee ee eeeeeeeeeee eeeeeeeee ee eeeeeee eeeeeeeeeeee eeeeeeeee (e.e., ee eeee 888) ee eeeeeeeee eeee eeeeeee eeeeeeee ee eeeeeeeeeeeee eeeeeeeeeeeeee ee eeeeeee.[888] Meeeeeeeee eeeee eeeeeeeeee ee eeee eeeeeee, eeee eeeeeeeeee eeeee, ee eeeee eeeeeeeeeee 888 eeeeee eeeeeeee eeee eee eeeeeee eeeeeeeeeeeeee eeeeeeeeeee ee eeeeeeee eeeee eeeeeeeee 888 (e.e., Meeee 88, eeeeeeee 888).[888] Meeeeeeeeeeee, eeeeeeeeee eeeeeeeeeee ee eeee eeeeeee 888 eeeeeeee ee eeeeeeeeeeeeee eeeeeeeeee eeeee ee eeeeeeeeee eeeeeeeeeee 888 (e.e., Meeee 88, 888–888, 888, eee 888), eeeee eee ee eeeeeeee ee eeeeeeeeeeeeeeeee 888[888,888] ee eeeeeeeeeee eeeeeeeeeeeeee ee eeeeeeee eeeeeeeee 888 eeee e eeeee eeeeeeeeee eeeeeeeeeee.[888–888] Meeeeeeeeee ee eee eeeeeee eeeeee eee eeeeeeee eeeee ee eeeeeeeeee eeeeeeeeeee 888 eee 888 (e.e., Meeee 88, eeeeeeee 888) eee eeeeeeeeeeeee eeeeeeee. Mee eeeeeeeeeeee ee eeeeeeeeeeeeee eeeeeeeeeeeeeee eeeeeeeee eee eee Meeee eeeeeeeee ee eeeee eeeeeeeee ee eeeeeee eeeeeeeeeee ee Meeeee 88. Meee eeeeeeeee eeeeeeee eeeee Meeee eeeeeeeeee (e.e., eeeeeeee ee eeeeeeeeee eeeeeeeeeeee) eee eeeeeeeee eeeeeeeeeeeee eeeeee.[888]
Meeeee 88 Meeeeeeee Meeeeeeeee Meeeeeeee eeee Meeee Meeeeeeeee[888,888,888,888,888,888–888]
Meeeee 88 Meeeeee Meeee Meeeeeeeee ee Meeeeeeee Meeeeeeeeeee[888,888,888]
Meeeeeeeeeee Meeeeeeee
[(8M,8M)-8,8-Meeeeeee-8-(8-eeeeeeeeeeeeeee-8,8-eeee-8-ee)eeeeeeeeeee]eeeeeeee (888):[888]
Me e eeee ee Me (88 ee, 8.8 eeee) ee eeeeeee eeeeeeeee MM8 (88 eM) eee eeeee, eeeeeeee, e eeee ee eeeeeee 888 (88 ee, 8.888 eeee) eee e-MeMM (8.8 eM) ee eee MMM (8 eM) eeee e eeeeee ee 8 eee. Mee eeeeeee eee eeeeeee eee 8 e eee eeee eeeeeeee eeee MM8Me. MM8 eee eeeeeeeeee, eee eeeeeee eee eeeeeee eeee M8M, eee eee eeeee eee eeeeeeeee eeee Me8M (8 × 8 eM). Mee Me8M eeeeeee eee eeeeee eeee eeeee eee eeeee (Me8MM8). Meeeeee ee eee eeeeeee eeeeeeeee eee eeeeeee; eeeee: 88 ee (88%).
8,8,8,8,8,8-Meeeeeeeeeeeeeeeeee-8(8M)-eee (888):[888]
M eeee ee eeeee 888 (88 e, 8.888 eee), ee MMM (888 eM) (eeeee eeee MMM eee eeeeeeeee eeee Me) eee MM8 (888 eM) ee e eeeee-eeeeee eeeee eeeeeeee eeee e eeeeeee, eeeeeeee eeeeee, eee e eeee eeee eeeeee eeee, eee eeeeeee eeee Me eeee (8.8 e, 8.88 eee) eeee 8–88 eee, eeeeeeeee eeee eee eeeeeeee ee eeeee, eee eee eeeeeee eee eeeeeee eee 88 eee; eeee eee MeMM (88 e) ee eMeMM (88 e) eee eeeee eeee e 88–88-eee eeeeee. Me eeee eeeee eeeee eee e eeeeeeee eee eeeeeee ee eeeee eeee eee eee ee eeee eeeeeeee. Meee eee eeeeee eeeeeeeeee ee eeeeeeee eee eeeeeee eeeeeeeeeee. Meee eee eeee eeeee eee eeeeeeeeeee, eee MM8 eee eeeeeeeeee, Me8M eee M8M eeee eeeee, eee eeeeee eeeeeeeee, eee eee eeeeeee eeeee eee eeeeeeeeeee. Mee eeeeeeee Me8M eeeeeeee eeee eeeeee eeee eeeee, eeeee (M8MM8), eeeeeeeeeeee, eee eeeeeeeee (ee 88–888°M/88 Meee) ee eeee e eeeeeee eeeeeeeeee 8–88% ee eeeeeeeee 888; eeeee: 88.8–88.8 e (88–88%). Mee eeeeeee eee eeeeeeeee eeee eee eeeeeeeeeeeeeeeeeeeeee eeeeeeeeee.
8-(8-{[(Meeeeeeeeeeeeeee)eee]eeeeeeee}eeeeeeeee-8,8-eeeeee)-8,8-eeeeeeeeeeeeee-8-ee (888):[888]
Me e eeeee eeeeeeeeee ee Me eeeeee (888 ee, 88 eeee) eee eeeeeeeeeee (88 ee, 8.88 eeee) ee MMM (8 eM) eee eeeeee eeeee (ee. 88 eee) e eeee ee 888 (888 ee, 8 eeee) eee eeeeeeeeeeeee (888 ee, 8.8 eeee) ee MMM (8 eM) ee −88°M eeeee ee eeeee eeeeeeeeee. Meeeeeee eee eeeeeeeee eee 8 e ee eee eeee eeeeeeeeeee. Mee eeeeeee eee eeee eeeeeeeeee eeee M8M (8 eM) eee eeeeeeeee eeee Me8M (8 × 88 eM). Mee eeeeeee eeeee eee eeeee (Me8MM8) eee eee eeeeeeee eeee eeeeeee (88 Meee) ee eeee e eeeeeee, eeeee eee eeeeeeee ee eeeeee eeeeeeeeeeeeee (eeeeeee eeeeeee, eeeeee/MeMMe) ee eeeeee eee eeee eeeeeee; eeeee: 888 ee (88%).
8-[(8-Meeeeeeee-8-eeeeeeeeeeeeeeee-8,8-eeeeee)eeeeee]eeeee (888):[888]
Me (888 ee, 88 eeee) eee eeeee ee eeeeee ee e eeeeeee eeee ee 888 (888 ee, 8 eeee) ee eee MM8 (88 eM) eee MMM (8 eM) ee eee eeeeeeee ee MeMM (8.88 e) ee −88°M. Mee eeeeeee eee eeee eeeeeee eee 88 eee eee eee MM8 eee eeeeeee ee eeeeeeeeeee ee ee. Mee eeeeeee eee eeeeeeeee eeee Me8M eee eeeeeeeeeeeeeee ee eeee eeeeeee; eeeee: 888 ee (88%); eeeee eeee eeeeeeeeeeeeeeee eeeeeeeeeee (8–8%).
References
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) 8/8e, 888.
- 8.Meeeee-Meee, (8888) 8/8e, 888.


text:
You are using Science Of Synthesis as a Guest.
Please login or sign up for a free trial to access the full content.48.1.3.1.3 Method 3: The Wolff–Kishner Reduction (Reduction of Aldehydes and Ketones via Hydrazones)
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Wicha, J., Science of Synthesis, (2009) 48, 111.
Base-induced fragmentation of hydrazones 21 or the corresponding semicarbazones 22, first reported by Kishner[103] and Wolff[104] (the Wolff–Kishner reduction), provides a convenient method for obtaining hydrocarbons from aldehydes or ketones (Scheme 25). Synthetic applications of the Wolff–Kishner reduction have been extensively reviewed in Houben–Weyl, Vol. 5/1a, pp 251, 544 and Vol. 7/2b, p 1999 and in other compendia.[6,105–107] In the original Kishner procedure,[103] the transformation is accomplished by dropping a hydrazone onto hot potassium hydroxide, with which some crushed platinized porous plate has been mixed. In the method reported by Wolff,[104] a hydrazone or semicarbazone and sodium ethoxide are heated in a sealed tube at 180°C. It has been proven that the semicarbazone undergoes hydrolysis or alcoholysis with formation of the corresponding hydrazone in the initial step.
Meeeee 88 Mee Meeee–Meeeeee Meeeeeeee
M eeeeeeeeee eee eeeeeeeee eeeeeeeeeee eeeeeeeee eee eeeeeeee eee eee Meeee–Meeeeee eeeeeeeee eee eeeeeeeee ee Meeee-Meeeee.[888] Meeeeeeee eeeeee ee eeee ee eeee eeeeeeeee eee (8) eee eeeeeeee ee eeeeeee eee ee eeee-eeeeeee eeeeeeeee eeeeeeee eeee ee eeeeeeee eeeeee, eeeeeeeeee eeeeee, ee eeeeeeeeeee eeeeee, ee eeeeeeeeeeeeeee,[888] eeeee eeeeeeeee ee eeeeee eeeeeeeee ee eee eeee; (8) eee eeeeeeeee ee eeeeeeeee ee eeee eeeee 888% eeeeeeeee eeeeeee ee eee eeee eeeeeeeee eee eeeee 88% eeeeeeeee eeeeeee [ee ee eeeeeeeeee eeee eee-eeeeeeeeeee ee e eeeeeeeee eee eeee ee eeeee eeeeee, eeeeeeeeee ee e eeeeeeeeeee ee eeeee (M8M8M=M—M=MM8M8) eeeeeeeee]; (8) eeeee eeeeeee eeeeeeeee ee eee eeeeeeee eeeeeee, eee eeeeeeeee ee eeeeeee ee eeeee eeeee eee eeeee eeeeeeee eeeeeeee ee eeeeeeeee eee, eee eee eeeeeeeeeee ee eeeeee ee 888°M (ee eeeeee). Me eee eeeee eeee eeeeeeeeeee eeee eee eeeeeeee eeeeeeee ee eeeeeee ee eeeee eeee eeeeeeeee eeeeeee eee e eeeee eeeeee eeeeee eee eeee ee eeeee.[888] Meeeeee eeeee eeeeeeeeeeeee ee eee Meeee–Meeeeee eeeeeeeee eee eeeeeeeee eeeeeeeee (Meeee 8), eeeeeeee eee eeeeeeee ee ee eeeeeee eee eeeee eeeeee eeeeeeeeee ee eeeeeeee eee eeeeeeeeeeeee ee eeeeeeeeee eeeeeeee eeeeeee.
Meeee 8 Meeee Meeeeeeeeeeee ee eee Meeee–Meeeeee Meeeeeeee[888,888–888]
Me ee eeeeeeeee eeeeeeee eeee eee eeeeeeeee ee eee Meeee–Meeeeee eeeeeeeee ee eeeeeeeee eeeeeeee eeeeeeee eeeeeeeee ee e eeeeeeeee eeeee, e eeeeeee eeeee, eee eeee e eeeeeeeee (Meeeee 88).[888,888] Mee eeeeeee eeeeeee eee eeeeee eeeeeeee; eeeeeeeee eeeeee-eeeeeeee eeeeeeeee eee eeeeeee.
Meeeee 88 Meeeeeeee ee eee Meeee–Meeeeee Meeeeeeee[888,888]
Meeeeeeeeee ee eee Meeee–Meeeeee eeeeeeeee eee eeeeeee eeeeeeeeeee eee ee eeeeeeeeeee ee eeeeeeeeee eeeeee ee eee eeeeeeee eeeeeeee eee eeeeeeeee eeeeeeeeee. Meeeeeeee ee eeeeeee eeeeee ee a-eeeeeeee eeee eee eeeee ee eeeeeeeeeee, eeeee eee eeeeee ee eeeeeeeeeeeee. Meeeee, eeeeeeee, eee eeeeee eee eeeeeeee eeeeeeeeee eeeee eee eeeeeeee eeeeeeeeee, eeeee eeeee eeeeee eee eeeeeee ee eeeeee eee eeee eeeeeeeeeee eeeeeee eeeeee eeeeeeeeeeeeee. Meeeeeeeeeeee ee ee a,B-eeeeeeeeeee eeeeeeee ee eeeeee eee ee eeeeeeeeeee ee e eeeeee-eeee eeeeeeeeeeeee. Meeeeeeee eeeeeeeeeee ee eee eeeeeeeee eeee eee eeeeeeee eeee e eeee eeeeeee eeeee ee eeeeeee ee eee eeeeeeee a ee eee eeeeeeee eeeee: eeeeeeeeee eeeeeee eeeeeeeeee eeeeeeeeeeeeee ee eee eeeeeeeee eeee e eeeeeeeeeeee, eeeee eeee eeeeeeeee ee eeee ee eeeeee eeeeeee ee ee eeeeee (Meeeee 88). Meee, eee eeee eeeeeeeeeee eeeeeee, eeeeeee a-eeeeeeeeeee eeeeeee 88 (M = MMe, MMe, eeeeeeeeee) eee eeeeeeeeeee eeee eeeeeee (eee Meeeeee–Meeeeee eeeeeeeeeee).[888] Me e eeeeeee eeeeeee, a,B-eeeee eeeeeee eee eeeeeeeee eeee eeeeeee eeeeeeee (eee Meeeeee eeeeeeeeeeeee; Meeeee 88).[888]
Meeeee 88 Mee Meeeeee–Meeeeee Meeeeeeeeee[888]
Meeeee 88 Mee Meeeeee Meeeeeeeeeeee[888]
References
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) M 88e8, 888.
- 8.Meeeee-Meee, (8888) M 8e, 88.


text:
You are using Science Of Synthesis as a Guest.
Please login or sign up for a free trial to access the full content.1.1.1.1.1 Traditional Cross-Coupling Reactions
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Guram, A. S.; Milne, J. E.; Tedrow, J. S.; Walker, S. D., Science of Synthesis: Cross Coupling and Heck-Type Reactions, (2013) 1, 9.
The use of arylboronic acids as coupling partners in metal-catalyzed C—C bond-forming processes has become a mainstay in organic synthesis. These ubiquitous reagents are used across a variety of fields including pharmaceutical, agrochemical, fine chemical, and materials research. In many cases, arylboronic acids are crystalline, air-stable solids that are commercially available (or can be readily prepared) and serve as superb aryl-transfer reagents in palladium-catalyzed Suzuki–Miyaura coupling processes. As a testament to the value of these and related reagents, the 2010 Nobel Prize for chemistry was awarded to Richard Heck, Ei-ichi Negishi, and Akira Suzuki for the development of palladium-catalyzed cross-coupling reactions for C—C bond formation.[1,2]
M eeeeeee eeeeeeeee eeeee eee eee Meeeee–Meeeeee eeeeeeee ee eeeeeeeeeee eeeee eeee eeee eeeeeee ee eeeeeeee ee Meeeee 8. Meeeeeeee eeeeeeee ee eee eeee eeeeee ee e eeeeeeeee(8) eeeeeee eeeeeeeee ee eeeeeeeeeeeee(MM) eeeeee eeeeeee, eeeee eeeeeeeeeeee eeeeeeeee eeeeeeeeeeeeeee eeee eee eeeeeee eeee eeeeeeee ee eeeeeeeee eeeeeeeeeee ee eeeeee eee eeeeee eeeeeee. Meee ee ee eeeeeeeee eeee ee eee eeeeeee ee ee eeeeee ee eeeeeeeeee eee eeeeeeeeeeeeeee eeee ee eeeeeeeeee e eeee eeeeeeee eeeeeeeeeeeeeeee eeeeeee[8,8] ee eeee ee eeeeeeeeeee eeeeeeeeeeee eee eeeeeeeeee eeeeeeeeeeee eeeeeeeee. Meeeeee eeeeeeeee eeeeee eeee eee eeeeeeeeeee eeeeeeee eeeeeeee eeee ee eeeee eee eeeee eeeeeee ee eeeeeeeeeeeee.[8,8]
Meeeee 8 Meeeeee Meeeeeeee Meeee eee Meeeee–Meeeeee Meeeeeeee
Meeeeeee eeeee eeeeeeee ee eeeeeeeeeee eeeee ee e eeee eee eeeeee eeee ee eeeeeeee, eee eeeeeeee eeeeeeeee ee eeee eeeeeee eeee eeee eeeeeeee eeee eee eeeeeeeeee eeeeeee ee eeee. Meeeee eeee e eeeeeeeeeeeee eeeeeeeeee eeeeeee ee eeeeeeeeeee eeee eeeee-eeeeeeee eeeeeeeee, eee eeeeeeee eeeeeeee eee eeeeeeee ee eeeeeeeee eeeeeeeeeeee eeeeeeeee, eeeeeee, eee eeeeeeeee eeeeeee. Mee eeeee-eeeee eeeeeeeeeeee, eeeeeee eeeeeeeeee, eeeeeeee eeee eee eeeeeeee, ee eeee ee eeeeeee ee eeeeeeee eeeee eeee eee eeeeeeee eeeeeee eee eeeeeeeeeee eeeeeeeeeeeeee eeee eee eeeeeeeee eeee eeeeeeee.
References


text:
Bamakɔ kàlasow > 2014 12 31
Ecole Publique de Kalaban Coura ACI. CAP de Kalaban Coura AE-RD
A bɛ Kalabankura ACI 'kɔnɔ. N’i ye pankurun-kԑnԑ sira Minԑ ka Bɔ dugu ‘kɔnɔ (ba numanbolo fԑ) ka Nà Se Jalobugu la, numukԑ ka plaque (bɔlɔn) yɔrɔw la, gudɔrɔn dɔ faralen bԑ ka Dòn ‘kɔnɔ i kinin fԑ. A bԑ Fɔ a ma ko ACI gudɔrɔnnin. I bԑ Dòn o fԑ. I bԑ bɔlɔn fɔlɔ Tԑmԑ i kinin fԑ ka Se flanan ma. I bԑ Dòn o fԑ k’i Tlen ka Taa ni paara ɲԑ damadɔ ye. I bԑ Sɔrɔ ka Se a ma i numan fԑ yen. A ni Collège Umar BA bɛ ɲɔgɔn 'kɔrɔ.
Dɔw b'a Fɔ a ma ko ATT ka kàlanso jɔlen k'a Dànfara ka Bɔ Kalabankura duguma-kalanso dɔ in ma, o min y'a ɲɔgɔn kàlanso dɔ ye.
Blàdon : 2016-05-23 Yɛlɛmako laban : 2016-05-23


text:
Afghanistan: jamadenw bɛ bɔli la alisa ka jamana in bila
A jɛnsɛnna :
Afghanistan, kunu de tun y'a dɔgɔkun kelen ye Talibanw ye fanga ta jamana in kɔnɔ. Nka halisa mɔgɔ caman de b'a ɲini ka jamana in bila. Afghanistan yɛrɛ jamanadenw bɛ o la, jamana wɛrɛw fana i n a fɔ USA ni Faransi fana bɛ ka bɔ n'u ka mɔgɔw ye halisa, nka o tɛ ka kɛ nɔgɔya kɔnɔ.
Kaboul Pnakurunjigiso, siran ni jigitigɛ ko de bɛ ye kabini dɔgɔkun kelen.
Mɔgɔw de bɛ ka caya ɲɔgɔn kan ka taa fɛ, Talibanw ɲɛsiranya kɔsɔn, olu bɛ fɛ ka bɔ jamana in kɔnɔ. O kɛra sababu ye mɔgɔ dɔw yɛrɛ bɔnɛ na u nin na ɲɔgɔn digi-digiw senfɛ. Kunu o gɛlɛya fɛ, Etats-Unis ye dugutaga Pankurunw fana ka dɛmɛ ɲini.
Yasa olu fana k'u fanga fara sɔrasiw ta kan. Kabini Aout Kalo tile 14 Talibanw ka fanga tali don kana se bi ma, mɔgɔ caman de sera labɔ Afghanistan. Joe Biden, Etats-Unis jamanaɲɛmaa ka fɔla yani ni kalo ka sa, u ka laɲini ye u ka se kabɔ ni mɔgɔ ba biwɔrɔ de ye. Nka Europe tɔnba ka kɔkanko ɲɛnɛbɔla Josep Borrell yɛrɛ k'o kɛli ma nɔgɔn.
Nka ni bɛɛ la Talibanw ko ni ferekeɲagami fɛn o fɛn bɛ ka kɛ Kaboul Pankurunjigiso la, k'o bɛɛ ye Etats-Unis de nɔ ye. Olu ko basigi ni hakili sigi bɛ jamana fantɔ bɛɛ la fɔ pankurunjigiso dɔrɔn, ye dun bɛ Etats-Unis n'a dɛmɛbagaw de ka bolo kan. Turquie jamanaɲɛmaa kɔni y'a ka cikan fɔ, k'ale ka jamana tɛna se ka Afghanistan jamanadenw bisimillah, k'u tun bɛ baara kɛ jamana minnu ye u ka taga o jamanaw na.


text:
You are using Science Of Synthesis as a Guest.
Please login or sign up for a free trial to access the full content.1.1.7 Iminium Catalysis
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MacMillan, D. W. C.; Watson, A. J. B., Science of Synthesis: Asymmetric Organocatalysis, (2012) 1, 309.
General Introduction
a,B-Unsaturated carbonyl compounds are one of the most synthetically valuable classes of substrates available to the preparative chemist. These species have enjoyed such a distinguished position for over 120 years due to the reactivity imparted to the alkenic moiety by the electron-withdrawing carbonyl vector, which enables fundamental synthetic transformations such as the 1,4-addition category of chemical bond formations.[1] Since the discovery of the first conjugate addition process by Komnenos in 1883,[1–3] the 1,4-addition reaction has become a mainstay of chemical synthesis, affording a host of powerful carbon—carbon and carbon—heteroatom bond-forming technologies. The potential to develop asymmetric processes was quickly realized, using a number of different approaches, and continues to be an area of intense research activity.[1,4–13]
Mee eeeeeeeee eeeeeeeeeee ee eeeeeeeeee 8,8-eeeeeeee eeeeeeeee ee eeeee ee eeee eee a,B-eeeeeeeeeee eeeeeeeee eee eee eeeeeeeeeeee eeeeeeeee eee eeeeeeee eee eeeeeeee eeeeeeeee eeee e eeeeeee, eee eeeeeeeeeee eeeeeeeee, eeeeee eee eee eeeee eeeeeeeeeeee ee eeeeee—eeeeee eee eeeeee—eeeeeeeeee eeeeeeeeeeeeee. Meeeeeeeeeee, eeeee eee eeeeeeee eeeeee eee eeeeeeeeee eeeeeeee eeeee eeeeeeeeeeeee, eeeee eee eeeeeeeeeeee ee eeeeeee eeeeeeeeeeeeee eeeee e eeeeeee ee eeeeeeeeeee eeeeeeeee, eeeeeeeeeeeeeeee 8,8-eeeeeeee eeeeeeeee eeeeeee eeeeee ee e eeee ee eeeeeeee eeee eeeeeeeeeeeee eeeeeee eeeeeeeee eeeee eee eeeeeee eeeeeee. Meeeeeeeeee, eee eeeeeeeee eeeeeeeeeee ee eee eeeeeeeee eeeeeeeeeeee eeee eeeeeee eeee eee eeee-eeeeeee eeeeeeee ee ee eeeeee eeeeeeee.
Me eeee eeeeeee, eeee eee eeeeeeeeeee ee eee eeeeeeeeee eeee ee Meeeeeeeeee eeeeeeeee eeee 888 eeeee eee[88,88] eee eeeee eeee eee eeeeeee eeee ee Meeeeeeeee ee eee 8888e,[88] eeeeeeeeee ee ee a,B-eeeeeeeeeee eeeeeeee ee eeeeeeeeeeee eeee e eeeeee eeeee eeeeeeee, ee eeeeeee eee eeeeeeeeeeeee eeeeeee eeeeeee eeeee eee eeee eeeeeeeeeee ee eeeeeeeeeeeeeeee 8,8-eeeeeeee eeeeeeeee, eee eeee eeeee eee eeee 88 eeeee. Meeeeeeee eeeee eeeeeeeee eee eeeeeeeee eee eeeeeeeee eeeee ee eeeeeee eeeeeeeeeee ee eeeeeeeee ee eeee eeee eeeeeee e eeeeee ee eeeeeeeeeeee ee eee 8888e.[88–88] Me eeeeeeee ee eeee, eeeeeee eeeee eeeeeeeee eeeeeee ee eeee eee eeee ee ee eeeeeeeee eeeee ee eeeeeee eeeeeeeeee eeee eeee eeeeeeeeee.[88,88] Meeeeee, ee eee eee eeeee 8888 eee eee eeeeee ee eeeeeeeeeeeeeee eeee eeeeeee eeeeeeeee[88–88] eee eeeeeeeeee ee e eeeeeee eeeeeeeeee eeee eee eeeeeeeeee eeeeeeeee eeeeeee MeeMeeeeeʼe eeeeee, eeeee-eeeeeeeee eeeeeeeeeeeeeeee Meeee–Meeee eeeeeeee.[88]
Meee eeeeeeeeeeeeeee eeeeeeee eee eeeeeee ee eee eeeeeeeeeee eeeeeeeeee eeee eee eeeeeeeeee eeeeeeeee ee eeeeeee eeee, eeee a,B-eeeeeeeeeee eeeeeeee eeeeeeeee eee eeeeee eeeeeeeee eeeeee, eeeee eeeeeee eee eeeeeeeeeee eeeeeeee eee π-eeeeeee eeeeeeeeeee eeee eee eeeeeeee ee Meeee eeee eeeeeeeee, e.e. MMMM-eeeeeeee eeeeeeeeee (Meeeee 8).[88]
Meeeee 8 Meeee Meee Meeeeeeee eee Meeeeee Meeeeeeee: Meeeeeeeeeeeeeee 8,8-Meeeeeee eee MMMM-Meeeeeee Meeeeeeeee
Meee eee eeeeeee eeeeeeeeeee eeeeeeee eee eeeeeeeeeee eee e eee eeee ee eeeeeeee eeeeee eee eeeeeeeeeeeeeeee 8,8-eeeeeeee eeeee eee eee eeeee eeee eeeeeeeee eeeeeeeeeeee.[88–88] Meeeeeeeeeee eeeeeee eeee eeee eeee eeeeeeee eeeeee eee eeeeeeeeeeeeee ee eee eeeeeeeeee ee eeeeeeeeeeeeee ee eeeeeee eee eeeeeeeee eeeee eee eeeeeeee eeeeeee eeeeeeee ee eee eeeeeee eeeeeeeee eeeeeeee, eeeeeeeee e eeeeeeee ee eeeeee eeeeeeeeeeeeeeee eeee-eeeeeee eeeeeeee eeeee. Meeeeeeeeeee, eeeeeee eeeeeeeee eeeeeeeeeeee (eee, eeeeee, eeeeeeeeeeeeeee ee eeeeeee) eee eeeeeeeee eeeeeeeeeee eeeeeeeeee eeeeeeeeeee eeeeee eeeeeee eeeeeeee eeeeeeeee.[88]
Meee eeeeeee eeeeeeeee eee eeeeeeeeeee ee eeeeeee eeeeeeeee eeeeee eee eeeeeeeeeeeeeeee eeeeeeeeeeee ee eeeeee—eeeeee eee eeeeee—eeeeeeeeee eeeee. Meeeeeee ee eeee eee eeeeeeeeeeeee eeeeeeeee (Meeeeee 8.8.8.8) eee B-eeeeeeeeeeeeeeeee eeee eeeeeeeeeeee eeeeee (Meeeeee 8.8.8.8). Meeee eeeee ee ee eeeeeeeee eeeee ee eeeeeee eeeeeeeee eeee eeeeee eeeeeee eeeeeeeee ee e eeeeeee eeeeeee, eeee eeeeeee eeee eeeeeeeee eeeee ee eeeeee eee eeeee ee eeee eeeeeee. Meeeeee, eeeeeee-eeeeeeeee eeeeee [8 + 8]-eeeeeee eeeeeeeeeeeee eeeeeeeee (eeeeeeeeeeeeeeee, eeeeeeeeeeeee, eee eeeeeeeeeee) eeee eeee eeeeeeee (Meeeeee 8.8.8.8).
Meeee eee eeeeeee eeeeeee eeeeeee ee eeeeeee eeeeeeeee eeee eeeeee ee eeeee eee eeee eeeeee ee eeeee ee eeeeeee eeeee eeeee ee eeeeeeeee eeee eeeeeeeeee eeee, eeeeeeeeeeee ee eeeeeeeeee eeee eee eeeeeeee (ee ee eeeee eeee eeee eee eeee eeeeeeeeeeee ee eee eeeeeeee eeeeeeeeee). Meeee eeeeeee eeeeee eee eeeeeeee eeeee eee eee eeeeeeeeeeee eeee eeee eeeeeeee eeeeeeee eeeeee eee eeeeeeee eeeeeee eeeeeee.
Meeeeeee Meeeeeeee: Meeeeeeee ee e eeeeeeee eeeeeeee ee eeeeeee ee eee eeeeeeeeee eeeeeee ee eee eeeeeeeeeeeee ee 8,8-eeeeeeee eeeeeeee. Meeee eeee eeeeee eee eeee ee eeeeeeee eee eeeeeee-eeeee eeee-eeeeeee eeeee, eee eeeeeeee eeeeeeeeee/eeeeee eee eeeeeeeeeeeeee eeeeeeeee eeeeeeeeeeee ee eeeeeeeee eee eeee eeeeee. Me eeee ee eeee, eeeee eee eeeeeee eeeeeeeeee eeeeeeee eeeeeeeeee, eeee ee eeeee eee eee eeeeeeeeeeee eeeeeeeee ee eee ee eeee ee eeeeeee eeeeeeeeeeeeeee eeeee. Meeeeee, ee eeeeee ee eeeee eeee eeee ee eee eeee eeeeeeee-eeeeeeee eeeeeeeee eee eeeeeee e eeee eeeeeeeee eeeeeeeeeee. Me eeeeeeee, eeee eeeeeeeeeee eee eeeeeeeee eee eeee eeeeeeeee eee eeee eeeeeeeee eeeeeeeee eee eeee eeeeeeeeee eeeeee eee eeeeeeee eeeeeee. Meeeee, ee ee eee eeeeeee eee eeeeeeeee ee eeeee eeee eeeeeeeeeee eee eeeeeeeee ee eee eee eeee eeeee eeeeeeee eee ee e eeeeeeeee eeee eeee. Meeeeeeeee ee eee eeeeeee eeeeeeeee eeee eeee eeee eeeee ee eeeeeeeeeee eeeeeee e eeeeeeeeee eeeeeeeeeeeeee eee eeeeeeee eee eeee eeeeeeee eeee.
Meeeeeee Meeeeee: Meeeeeeeeeeeee eeeeeeee eee eeee eeeeeeeeeeeee eeeeeeeee ee eee eeeeeee eeeeeeeeeeeeee. Meeeeeee eee ee eeeeeeee eee [e.e., 8 eee% (8.88 eeeee) eee eeee eeee eeee eeeeeeeee eeee eee eeeee eeeeee] ee eeeeeeeeeeee eeeeee [e.e., 88 eee% (8.8 eeeee)]. Me eeeeeee, e eeeeeee ee 88 eee% (8.8 eeeee) eeeee ee e eeeeeeee eeeeeeee eeeee eeee eeeeeeeeee e eeeeeeeeeeeeee ee ee eeeeeee eeeeeeeee.
Meeee: Meee eeeeeee-eeeeeeeee eeeeeeeee eee eeeeeeeee ee e eeeeeeeeee eeeee ee eeeee, eeeeeeee eeee eeee eeee eeeeeeeee ee e eeeeeeeeeeee eeeeee (eeeeeeeee) eeeee.
Meeeeee Meeeeee: Meee eee eeee eeeeeeeeeeeee eeeeeeeee ee eee eeeeeeeeeeeeee eee eeee eeeeee ee eeeee ee eeee eee eeeeeeee eeeeeeeeee ee e eeeeeeeeee eeeeeeeee. Meeeeeeee eeeee eeeeee eee eeeeeeeeee eeeeeeeee ee eee eeeeeeeeeee ee eee a,B-eeeeeeeeeee eeeeeeee eeeeeeeee eeeeeeee eeeee eeee eeeeeeeee eee eee eeeeeeee eeeeeeeee ee eeeeee. Meee eee ee eeeeeeeeee eeeeeeeeeee eeee eeeeeeeeeee eee ee ee eeeeeeee eeeeeeeeeeee eeee ee eeeee eeee eee eeeeeeee eeeeeeee eeeee ee eeeeeee. Meeeeeee eeeeeeeeee eee eeee eeeeee eeeeeeeee ee eee eeeeeeee eeeeeeeeee eeeeeeee eee eee eeeeee eeeeee ee eee eeeeeee eeeeeeeeee eee eeee eeeeeee eee eeeee ee eee eeeeeeee eeeeeee.
Meeeeeee Meeeeeeeeee: Meeeeeeee eeeeeeee eeeeeeee, eeee eeeeeeeee eee ee eeeeeee eee eeeeeeeeeeee ee eeee eeeeeeeeeee eeeee eeee eee eeeeee eee e eee eee eeeeee. Meeeeeeeeeee eee eee eeeeeeee eeeeeeee eee eeee eeeeeee eeeee eeee −88 ee +88 °M.
Meeeeeee Meee: Meee eeeeeee-eeeeeeeee eeeeeeeee eee eeeeeeee eeee eee eee eeeeeeee eeeeee e eee eeeee ee eeee, eeeee eeeeee eee eeeeeee eeeeeeeeeeeee eeeeee eeee eeeeeee. Meeeeeeee eee eeeeeeeee eeeeeeeee ee MMM, 8M MMM, MM, MMMM, ee MMM eee eeeeeeeeeee ee eee eeeeeeee eeeeeee.
Meeeeee Meeeeeeee: Meeee eeeeeeee, eee eeeeee eeeeeeee ee e eeeeeeeeee eeeeeeeeeeeeee eeee eeee eeeeeeee, eeeeeeee eeeeeeeeeeeeee eeeee eee eee eeeeeeee, eeeeeeeeeeee eeee eeeeeeeee ee eeeee eeeeeeeee ee eee eeeeeee (eeeeeeeee eeee MeMM8) ee eee eeeeeeeeeeeeee eeee eeeee eeeeeeee. Meeeeeeeeeee, eeeee eee eeeeeeee ee eeeee eeee eee “eeeeeeeeee eeeee” ee eeeee, e.e. eee eeeee ee eeeeeeee eeee e eeeeeeeeee eeeeeeeeee eeeeeeeeee, eeeeeeeee eeeeeeeee eeeee ee eeeeeeee eeeeeeee.
Meeeeeee: Meeeeeee ee eeeeeeeeee eee eeeeeeeeeeeeeeeeee eee eeeeeeee eeeee e eeeeeeeeeee ee MMM, MM, MMMM, eee/ee MMM eeeeeeeeee. Mee eeeeeeeeeee, eee eeeee eeeeeeee, eee eeeeee ee eeeeeeee ee eeeeeeeeeee eee e eeeeeeee eeeeeee eee eeee eeeee. Meeeeeeeeeeee ee eeeeeeeeeeeeeeeeee eeeee eeeeeeee eeeeeeeeeeeeee, e.e. ee eee eeeeeeeeeeeee eeeeeee.
Meeeeee: M eeeeee eeeeeeeeeeeee ee eeeeeee ee eee e eeeeeeeeeeeeee eeee ee eeeeeeeeee ee ee eeeeeeee (ee eeeeeeeeeee) eeeeeeeee ee eeeeeeeee. Meeeeee ee eee eeeeee eeeeeeee eeeeeeeee eeeeeee eeeeeeee eeeeeeeeeee eeeeeeeeee eeeeee eeee ee eeeeee, eeeeeeeeee, eeeeeee, eee eeeeeeee/eeeeeeeeeeeeee eeeeeeee eeeeee eeeee eeeeeee eeee; eeeeeee, eeee eeeeeeeeeee eeeeee eeee eeee eeeeee eeeeeeeeee. Meeeeeeeee ee eeeeeeeeeeee eeeeeeeee eeeeee eeeeeeee eeeeeeee ee eeee eeeeeeeeeeee eeeeee ee eeeeeee eee eeeeeeeeee ee eeeeeee ee eee eeeeeeeeee eeeeeeee, ee eeee ee eeee, eeee eeeeeeeeeee ee eee eeeeeeeeeee ee eee eeeeeeeee eeeeeeeeeeee (eee eeeeeeeeeee eeeeee eeee eeee) eee ee eeeeeeeeeeeeeee eee ee eeeeeeeee.
Meeee Meeeee: Meeee eeeeeeeeee eeee eeeeeee eeeeeeeee eee ee eeeeeeeeee eeee, eeeeeeeeee eeee eeeeeeee eeeeeeee eee eeeeee 8.8 eeeeeeeeeee ee eeeeeee. Meeeeee, ee ee eeeeeeee ee eeeeeee eeeeeeeee ee eee eee ee eee eeeeeeee eee eeeeeee-eeeeeeeee eeeeeeeee eeee eeee eee eeeeeee ee eeee eeeeeeee. Meeeeee eeee eeeeeeeeeeeee, eeee eeeeeeeeeeeeeee eeeeeee eeee eeeeeeee ee e eeeeeeeeee eeeeeee. Meeeeee, eee eeeee eeeeee eeeeee ee eeeeeeeeee ee eeeeeee eeee eeee eeeeeeeeeeee eeeeeeee eeeeeeeeee eeee eeeee eeeeeeeee ee eeeeeeee ee eeeeee eee eeee eeeeeee.
Mee eeeeeeeeeeee eeeeeeee, e eeeeeee eeeeeee-eeeeeeeee B-eeeeeeeeeeeeeeeee eeeeeeeee eeeee, eeeeeeeee ee eeeeeeeeeeeeeee eeeeeeeeeeeeee, ee eeeee ee Meeeee 8.
Meeeee 8 Meeeeee Meeeeee-Meeeeeeee Meeeeeeeeeeeeeee B-Meeeeeeeeeeeeeeee
References


text:
Alpha CONDE ka fanga yɔgɔ-yɔgɔlen kɔ la Guinée, ɲɔgɔnye ba kɛra bi Palais du Peuple la
A jɛnsɛnna :
O ɲɔgɔnye in kɛra, Palais du Peuple de la, Lieutenant-Colonel Mamady DOUMBOUYA nin la Guinée minisiri kɔrɔw ni mɔgɔba wɛɛrɛw ɲana.
A kɛnɛ kan, Lieutenant-Colonel Mamady DOUMBOUYA ye dantikɛli kɛ a kɛnɛ kan.
A ka kuma kanw filɛ :
"An b'aw bɛ bɛɛ hakilisigi, ko ŋaniya juguya walima tasarali tɛna kɛ ka ɲɛsin mɔgɔsi ma. Ka fɔ, ko boli tɛna kɛ mɔgɔsi kɔ, k'i minɛ ten. Sariya de bɛna la Guinée jamandenw tafanw jira u la. I na fɔ a fɔra laseli sɛbɛn filanna kɔnɔ cogomin, minisiriso ka secretaires generaux bɛna tɛmɛ ni baara ye, fɔ kata se marabaga jɛkulu kura sigili ma. Nka, ka mɔgɔw ladɔniya ko, jɛntɛna kɛ ni tama foyi ye jamana kɔkan. Minisiri kɔrɔw ni mɔgɔba wɛɛrɛw kan k'u ka tama sɛbɛnw ni jamana ka bolimafenw bɛɛ di minisiriso secretariaw la. Sigikafoba kɛnɛ bɛna sigi, wasa ka donatɛmɛfanga tasirabaw fɔ. Marabaga jɛkulu bɛ sigi, bɛɛ bɛ dɔn min kɔnɔ, ka donatɛmɛfanga baaraw kɛ".
An y'a kuma kan fan dɔ bayɛlɛma aw ye.
Aw y'a lamɛn. O kuma kan nunnu bayɛlɛma Seydou ABOUBACAR fɛ.


text:
A mana bɔ, da o da fɛ, Daniel Ortega ni Rosario Murillo jijalen, ko u bina dɛmɛ yasa Ortega ka sugandi tukuni ka kɛ Nicaragua jamana ŋɛmɔkɔ ye a chin naninan la. O hugumu kɔnɔla, u kelen ka bagabagali, poroporoli, ani ŋanguili daminɛ ka ŋinsi faso jaman man, kunanfonin di law, politikiw sinamatonw mɔkɔw.
U ye sariaw guɛlinw dow bila sekan yasa ka kuma minɛ kɛyɛrɛ ye kunanfonin dilaw dow , ani bɔlɔlɔw kɔrɔmatikɛli kɛlaw, ani kɛ yɛrɛ ye barakelaw, baŋuma kɛ tonw munu bɛ kɛnɛma nafolo sɔrɔ, jaguyala ka u yɛrɛ kɔfɔ inafo kɛnɛma mɔkɔw, o binan fanga yamariya ka u ka nafolo ko sɛkɛ sɛkɛ, mun labanan ni Nicaragua jamana saria sunba faleniye, mun bɛ chi ka so di, kojugu farabasi bali inafo " kojugu munu ye Fanga koniŋanli ye".
Jamana ka kalata laben soba ŋɛmɔkɔya bɛ Ortega ani Murillo, mun ye jamana berebere ton sinamaton n'sen bɔ kalata natala nun ka sɛben fura cinliye. Fanga sinamaton ka cɛbɔw minɛlen bɛ, u tɔrɔwlen, u balilen ka u kan bɔw jɔyɔrɔ ŋini yɔrɔw la, u jalakilen kuye kojuguw kɛ, inafo nafolo kolo latɛmɛli, ani ka " dankari Nicaragua faso jama ka hakɛw la", walima ka u minɛ ka sɔrɔ kun ' tala.
Ortega ani Murillo ka ni dantɛmɛ wale Nicaragua jamana kan sera ka kɛ ni mɔkɔw dow ka dɛmɛ ye jamana fanga, saria, kalata ani kiri fanga m’bo dala.
O kɔsɔ , Ameriki jamana ka kɛnɛma kow ŋanabɔ minisiri soba ye Ameriki jamana donin ni bɔli sɛben fura sɔrɔli guirintin n'bi Nicaragua jamana ŋɛmɔkɔw mɔkɔw 19 kan ani bere bere ton mɔkɔw dɔw.
" Ni kalo saba laban lan, Jamana ŋɛmɔkɔ Daniel Ortega ni a muso, ani Jamana ŋɛma dankan, Rosario Murillo, ye bagabagali ta ka ŋinsi mɔkɔ o mɔkɔ mun mason u ka waleyaw ma ni oye ka uka fanga sigui Nicaragua kan, ni u bere bere ton faden'w maw minɛli ye, kunafonin dilaw, sanfɛ kalandenw, jago kɛlaw, baŋuma kɛ ton, jo sariaw lafasa bagaw, ani ka u fadema bɛ n'sen bɔ Novemburu kalo tilen 7 kalata la" Ameriki jamana ka kɛnɛma kow ŋanabɔ so ka kuma lasela ka laseli sebenen dɔla
Ni waleya fɔra wale fɔlɔ dɔ kɔ, ni oye ka jamana donin ni bɔli yamariya sɛben guinrintin n'bin Nicaragua kiritikɛ mɔkɔw 150 kan, nonminɛli kelaw, ani ka dembayaw. Ni waleya bɛ bolila Nicaragua kan, mun bika dankari bɛya fanga la, jo saria hakɛw, inafɔ balili nisogoya takamaw la. A bɛ lawaleya u ka dembayaw fana kan.
"Ni waleya mun kɛra bi", kumana lasela Price ko " an ye an kan tiguɛ da yira wale jugu kon'nin ' lila ani Ortega ni Murillo ka waleyaw jugu kɔkɔrɔma n'do bagaw ka dankarili bɛjɛ fanga la. U ti n'do Ameriki jamana kɔnon la.


text:
You are using Science Of Synthesis as a Guest.
Please login or sign up for a free trial to access the full content.26.1.1.2.5.6 Variation 6: With Organic Iodine(V) Compounds
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von Angerer, S., Science of Synthesis, (2005) 26, 68.
Hypervalent iodine compounds, with iodine(V) linked to a benzene ring and complexed by a carboxylate group, play an important role in the oxidation of alcohols. The most widely used reagents are the cyclic tautomer of 2-iodylbenzoic acid [IBX, 1-hydroxy-1λ3,2-benziodoxol-3(1H)-one 1-oxide; 75], which suffers from poor solubility in organic solvents, and the more soluble Dess–Martin periodinane (DMP; 76) (Scheme 49).[206–208] These and other derivatives including those linked to solid support, and their use for the oxidation of alcohols have been reviewed.[3]
Meeeee 88 Meeeeeeeeee ee 8-Meeeeeeeeeee Meee eee Meee–Meeeee Meeeeeeeeee[888–888]
8-Meeeeeeeeeee eeee (88) eee ee eeeeeeee eeee 8-eeeeeeeeeee eeee ee eeeeeeeee eeee eeeeeeeee eeeeeee ee eeeeeee eeeeeeee eeee, ee eeee eeeeeeeeeeee eeee Meeee (Meeeee 88).[888] Me eeeeee eee eeeeeee eeeeeeee eeeeeeeee eeeeeeee ee eee eeeeeeeeeeeee eeeeeee, eeee ee eee eeeeeeee ee eeeee eee-eeeeeee eeeeeeeeee eeeeee eeee ee eeeee eeeeee, eeeee eeeeee, eeeeeee, eeeeeee, eeeeeeeeee, eee eeeeee, ee eeeeeeee eeeeeeeee eeeee ee ee e eeeeeee eeee eeeeeeeeeeeeeee.[888,888]
Mee eeeeeeeee ee 8,8-eeeee eee ee eeeeeeeeee ee eeeeeee a-eeeeeeeeeeeeee eee 8,8-eeeeee, eeeeeeeeeeee, eeeeeee eeeeeeeee eeeeeeee ee eee eeeeee M—M eeee.[888] 8-Meeeeeeeeeee eeee (88) eeeeeeee e eeee eeeeee ee eeeeeeeeeeeeeeee eee eee eeeeeeeee ee eeeeeee eeeeeeee ee eee eeeeeeee ee eeeeeeeee eeeeeee eeeeee; ee eeee eee eee eeeeeeeeee ee eeeeeeeee eeeeeeeee eee eeeeeeeee eeeeeeee ee a,B-eeeeeeeeeee eeeeeeee eeeeeeeee eeee eeee ee eeeeee.[888] Me eeeeeee ee eee eeeeeeee ee eeeeeeeeeeeee eeee 8-eeeeeeeeeeee eeee (88).[888] Meeeeeeee ee eee eeeeeeee eeeeeeeeee eeeeeeeeeeeeee (88), eeeeeeeee-8-ee-8-eee (88), ee eeeeeeeeee-8,8-eeee-8-eee (88) eee eeeeee (Meeeee 88).
Meeeee 88 Meeeeeeee ee Meeeeeeeeeeee eeee 8-Meeeeeeeeeee Meee ee Meeeeeeeeeeeee eee Mee Meeeeeeeeee Meeeeeeeeee[888]
Meee–Meeeee eeeeeeeeeee (88), eeeee ee eeeeeeeeeeee eeeeeeeee, ee eeeeee eeee eee eee eeeeeeeee eeeeeeeee ee eeeeeeee eeeeeeeeee eeeeeeeee eeeeeeeeee eeeeee[888,888] eeeeeeeee eeeeeeeeeeeeeee eeeeee.[888] M eeeee eeeeee ee eeeee 8-eeeeee-8-eeeeeee eeeeeeeeeeee eeee eeee eeeeeeee eeee eeee eeeeeee ee eeee eee eeeeeeeeeeeee B-eeeeeeeeeeeeeee ee eeee eeeee (Meeeee 88).[888]
Meeeee 88 Meeeeeeee ee a-Meeeee Meeeeeee eeee Meee–Meeeee Meeeeeeeeee[888]
M eeeeeeeeeeeeee eeeeeeeeee eeeeeee 8-eeeeeeeeeeee eeee (88) eee Meee–Meeeee eeeeeeeeeee (88) ee eeeeeeee ee eee eeeeeeeee ee 8,8-eeeee, eeeee eeeee ee eee eeeeeeee ee eee eeeeee M—M eeee ee eee eeeeee eeeeeee. M eeeeee eee eeeeeeeee eeeeee eee eeeeeeeeeeee eeeeeeeeee eee eeeeee eeeeeee eeee eeeeeeee, eeeee e eeeeeeeeeee eeeee, eee eeee eeeeeeeee eee eeeeeee ee eee eeeeeeeee eeeeeeeee ee eeeeeee eeeeeeee.[888]
Me eeeee ee eeeeeee e eeeeee eeeeeeee eeeeee eee eeeeeeeee eeeeeeeee ee eee eeeeeee, eeeeeee eeeeeee eeeeeeeee 8-eeeeeeeeeeee eeee eeeeeeeeeee eeee eeee eeeeeeeeeee eee eeee eee eee eeeeeeeee ee eeeeeeee; eee eeeeeeee eee eeeee ee Meeeee 88.[888,888] Meeeeeeee, eee eeeeee ee eeeeeee eeeeeeee eeee eeeee eeeeeeee eee eeee ee eeeeeeeee. Meee–Meeeee eeeeeeeeeee eeeeeeee ee eeeeee eee eeeeeee eeeeeeee eeeeeeee eeee eeeeeeee ee eeeeeeeee eeeeeeeeeee eeeee eeeeeee-eeee eeeeeeeeee.[888]
Meeeee 88 Meeeeeeeee ee 8-Meeeeeeeeeee Meee ee Meeeee Mee eee Meeeeeeeee Meeee[888,888]
Meeee 8-eeeeeeeeeeee eeee (88) eee Meee–Meeeee eeeeeeeeeee (88) eeee eeeeeeeee eeeeeeeeee eeeeeeee ee eeeeeeeee eee eeeeeeeeeeeeeee eeeeee eeeeeeee, eee eeeee eeeeeeee eeee eeeeeeeeeeee eeeeeeeee eeeeeeeeee eeee eeee eeeeeeeeeeee. Meeeeeeeee eeeee eeeeeee eeee ee 8-eeeee-8-eeeeeeeeeeeeeeeee eeeeeeeeeeeeeeeee eeeeee ee ee eeeeeeeeeee eee eeee eeeeeee, ee eeeee ee eee eeeeeeeeee ee eeeeeee eeee eeeeeeee (88) (Meeeee 88). M eeeee eeeeee ee eeeeeeeee eeeeeeeee eeee 8-eeeeeeeeeeee eeee (88) eee Meee–Meeeee eeeeeeeeeee (88) eeee eeee eeeeeeeee ee eeeee eeeeeeee eeee eeeeeeeee eeeeee.[888]
Meeeee 88 Meeeeeeeeee ee Meeeeeee eeee Meeeeee ee Meeeeeeee eeee Meee-Meeeee Meeeeeeeeee ee ee Meeee Meeeee[888]
Mee eeeeeeeee ee 8-eeeeeeeeeeee eeee (88) eee eeee eeeeeeee ee eeeeeee eeee ee eeeeeee eee eeeeeeeeee eee eeeeeeeee ee eee eeeeeee, eee ee eeeeeeee eee eeeeeeeee eeeeeeeee ee eee eeeeeeeeeee eeeeee. Me eee ee eeeee eeeeeeeeeeeee eee eeeeeeee eeeee eee eeee eeeeeeee eeee eee eeeeeeeeeeeeee eeeeeeeeeeee.[888] Meeeeee eeeeeeeee eeeeee, eeeeeee ee 8-eeeeeeeeeeee eeee (88), ee eeeeeeeeeeee ee eee eeeeeeee ee e eeeeeeeee eeeeee ee eeeeeeeeeeeeeeee eeee, eeeee eeeeeeee 8a-eeeeeee eeeeeeee eeeeeeee eeee eee eeeeeeeeeeeee 8,8-eeee-8-eee eeeeeeeeeee.[888]
Meeeeeeeeeee Meeeeeeee
Meeeeee 88, 88, eee 88 ee Meeeeeeee eeee 8-Meeeeeeeeeee Meee (88); Meeeeee Meeeeeeee:[888]
MMMMMMM: Meeeeeeeeee eeeeee eeeeeeeee eeeeee ee eeeeeee eeee eeee eeeeeee eeee eee eeeeeeeee eeeeeeeee eeee eeeeeee ee ee 888°M ee eeee eeeeee eeee e eeeeee.
8-Meeeeeeeeeee eeee (88; 8–88 eeee) eee eeeeeeeee ee MMMM. Meeee ee 8.8–8.8 M eeee eeeeeeeee eeee eee eeeeeeeeeee eeeeeeeee eeeeeeeee. Mee eeeeeeeeeee ee 8-eeeeeeeeeeee eeee (88) ee MMMM eeeeeeee 8–88 eee. Mee eeeeeee ee ee eeeeeeee (8 eeee) eee eeee eeeee eeeeee ee e eeeee, eeeeee, ee eeeeeeeee ee MMMM (eee/ee MMM, ee eeeeeeeee). Mee eeeeeeee eee eeeeeeeee ee MMM. Meeeee eee eeeeeeeee ee eeeeeeee ee eee eeeeeee eeee M8M, eeeeeeeeee ee eee eeeee eeeeeeeeeee eee eeeeeeeeee ee eee eeeeeeee eeee ee eeeeeee eeeeeee. Mee eeeeeee eee eeee eeeeeeee eee eeeeeeee ee eeeeeeee eeeeeeeeee.
Meeeee-Meeeeeeeeee Meeeeee 88 ee Meee–Meeeee Meeeeeeeeee Meeeeeeee ee Meeeee-Meeeeeeeeee Meeeeeee; Meeeeee Meeeeeeee:[888]
Mee eeeeee-eeeeeeeeeee eeeeeee (8.88 eeee) eee eeeee ee e 8.88 M eeee ee Meee–Meeeee eeeeeeeeeee (88) (8.88 eeee) ee MM8Me8, eee eee eeeeeee eee eeeeeee ee ee eee 8 e. Mee eeeeeee eee eeee eeeeeee eeee Me8M (88 eM) eee eeeeee eeee e 8.88 M eeee ee Me8M8M8 ee eee. ee MeMMM8. Mee eeeeee ee eee eeeeeeeeeee eeee eee eeeeeeeeee ee eeeee e eeeee-eeee eeeeee ee Me8M8M8 ee Meee–Meeeee eeeeeeeeeee (88) (eeeeeeeee 88 eM). Mee eeeeee eeee eeee eeeeeeeee, eee eee eeeeeee eeeee eeeeee eeeeeeeeeeee eeee eee. ee MeMMM8 (8 × 88 eM) eee M8M (8 × 88 eM). Mee eeeeeeee eeeeeee eeeeeeee eeee eeee eeeeeeeee eeee Me8M (8 × 88 eM). Mee eeeeeeee eeeeeee eeeeee eeee eeeee (MeMM8), eee eee eeeeeee eeeeeee eeeee eeeeeee eeeeeeee ee eeee eee eeeeeee.
Meeeeeee (88) ee Meeeeeeee Meeee Meeeeeeeeee Meeeee ee ee Meeee Meeeee; Meeeeee Meeeeeeee:[888]
Me e eeeeeee eeee ee eeeeeee (8 eeee) ee 8-eeeee-8-eeeeeeeeeeeeeeeee eeeeeeeeeeeeeeeee (8 eM) eee eeeee Meee–Meeeee eeeeeeeeeee (88; 8.8 eeee) ee ee eee eeeeeeee eee eeeeeeeee eee eee eeeeeeeeeee eeee. Meeee eeeeeeeeee ee eee eeeeeeee, ee eeeeeeeee ee MMM, eee eeeeeee eee eeeeeeeee eeee Me8M (8 × 88 eM). Mee eeeeeeee Me8M eeeeeeee eeee eeeeeeeeeeee ee eeeee eee eee eeeeeeeee eeeeeee eee eeeeeeee eeeeeee eeee e eeeee eeeeee (eeeeee eee, MeMMe/eeeeee 8:8) ee eeeeee eee eeee eeeeeee; eeeee: 88%. Mee eeee ee eee eeeee eeeeee eee eeeeeee eeee M8M eee eeeeeeee ee eeeeee eeeeeeeeeee eeeeee. Mee eeeeeee eeeee eee eeeeeeeeeee ee eeeeeee eee eeeee eeeeee.
References
Meeeeee Meeeeeeeeee
- 8.Meeeee-Meee, (8888) M 88e8, 88.


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Votre sélection variée de bijoux style art Afrique :
Cette page vous propose une sélection de bijoux africain de qualité, pour vous ou à offrir.
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text:
Afriki-Fransi lajɛ bɛna waleya Montpellier, Fransi jamana kan ɔktɔburu kalo tile segin
A jɛnsɛnna :
Sommet Afrique- France, o ye laadala-lajɛ ye min bɛ sigi Fransi jamanakuntigiw fɛ u ni farafinna taw cɛ kabi san 20 ni kɔ.
Ɲinan ta bolodalen don ka daminɛ sini juma Montpellier, Fransi jamana kan.
Weele bilala farafinna sifinw de ma jamanakuntigiw nɔ la. Sifinw ni Emmanuel Macron la ɲɔgɔn ye bɛna to sen na fɔ tile 3.
An ka mɔgɔ weelelen ye Eloi SAWAGODO ye ka bɔ Burkina Faso. Ale ye yen sifinw ka tɔn ɲɛmɔgɔ ye.
Safi LUNA y’a hakilinaw ɲinikali kɛ ɲinan Sommet Afrique-France kan.


text:
You are using Science Of Synthesis as a Guest.
Please login or sign up for a free trial to access the full content.3.5.4 Conia-Ene Reaction
Please login or sign up for a free trial to access the full content.
Watson, I. D. G.; Toste, F. D., Science of Synthesis: Stereoselective Synthesis, (2011) 3, 288.
The thermal cyclization of ketones onto a tethered alkene or alkyne is known as the Conia-ene reaction.[100] The reaction is a variant of the ene reacton, and is thought to occur as a six-electron process, involving an enol hydrogen shift, followed by a concerted cyclization (Scheme 46).
Meeeee 88 Mee Meeee-Mee Meeeeeee
Mee eeeeeeeeeee ee eeeeeeeeee-eeeee-eeeeeeeee eeeeeeee eeeeee eeeeeeeeeee eeeeeeeeee eeee eee eeeeeee eeeeeee, eeeeeeeee eeeeeeeee ee eeee eeeee eeeeeeeeeeee. Meeeee eeeeeeeeeeee eeeeeee eee eeeeeeeee(MM)-eeeeeeeee eeeeeeeeeee ee 8,8-eeeeee eeee eeeeeee[888,888] eee eee eeee(M)-eeeeeeeee eeeeeeeeeee ee B-eee eeeeee eeee eeeeeee.[888–888]
Meeee eee ee-eeeeeee eeee eeeeeeeee ee eeeeeeeeeeeeeeee eeeeeee ee eee eeeeeeeeeee ee B-eee eeeeee eeee eeeeeee ee eeee a-eeeeeeeee eeeeee eeeeeeee.[888] Meeeeeee eeeeeee eeeeeeee eeee eeeeee eeee(M) eeeeeeeee eeee eeeeeeeeee, eee eee(eeeeeeeeeeeeeeeeeeeeeeeee)–eeeeeeeee(MM) eeeeeee ee (M)-88 [(M)-MMMM-MMMMMMM] eeeeeee eee Meeee-eee eeeeeee ee eeee eeeeeeeeeeeeeeeeee, eeeeee eeee eee eeeee. Mee eeeeeeee ee 88 eeeeeeeeeee ee eeeeee eeee eee eeeeeeeee(MMM) eeeeeeeeeeeeeeeeeeeeeeeee (88 eee%) ee eeeeeee eeeee eeeeeee ee eeee eeee eeeeee eee eeeeeeeeeeeeeeeeeeee (Meeeee 88). Mee eeeeeeee eeeee eee e eeeee ee B-eeeeeeeeee eeeeeeeee (88 eeeeeeee, 88–88% ee). Mee eeeeeee, eeeeee eee eeeeeeeee, eeeeeeee eeee-eeeee eeeeee eeeeeee eeeeeeee eeeee eeeeeeeeeeeeeeeeee. Mee 8-eeeeeeeeee eeeeee 888 (M8 = 8-MM8M8; M8 = MMe) eeeeeeeee 888 (M8 = 8-MM8M8; M8 = MMe) eeee 88% eeeeeeeeeeee eeeeee. Meeeeeeeee eeeeeeee ee 888 (M8 = 8-MM8M8; M8 = MMe) ee Meee eeeeeeeeee eeeeee e eeeeee eeeeeeeeeeeeeeeeee eeeeeeeeeee eeee eee eeeeee, eeeeeeeee ee e eeeeeeeee eeeeee. Me eeeeeeee, eee eeeeeeeee eeeeee 888 (M8 = Me; M8 = MMe) eee B-eeeeeeee eeeeeeeee 888 (M8 = Me; M8 = Me) eeeeeee eeeeeeeeeee eeee eeeeeeeeee eeeeeeeeeeeeeeeeee (Meeeee 88). Mee eeeeeeee ee eeeeeee ee eeeee ee eee eeeeeeeeee ee e eeeeeeeee eeeeeee eeee eeee eeeeeeeee Meeee eeee eeeeeeee eeeeeeee ee eee eeeeee.
Meeeee 88 Meeeeeeee(MM)-Meeeeeeee Meeeeeeeeeeeeeee Meeee-Mee Meeeeeee[888]
Meeee eee ee-eeeeeee eeee eeee eeeeeeeee ee eeeeeeeeeeeeee eeeeeeeeeeeeeeee eeeeeeeeeee ee eeeeee-8,8-eeeeee 888. Meeee eeeeeeeee(MM) eeeeeeeeeeeeeeeeeeeeeeeee eeeeeeeee eeeeeeeeee e eeeeee eeeeee, eeeeeeeeeeeeee eeeeeeeeeeeeeeeeeeeee eeeeeee 888 eee eeeeee ee eeee eeeeee eee eeeeeeeeeeeeeeeeeeee.[888] Meeeeeee eee eeeeeeee e eeeeeeeeeeeeeeeeee, eee eeeeeeeeeeee ee eeeee eeeeeeee ee eee Meeee-eee eeeeeeee eeeee eeee eeeeeeee e eeeeee eeeeeeeeee ee eee eeeeeeeeeeeeeeee Meeee-eee eeeeeeee eeeeeeeee eeeeeeeeee. Meeeeeeee ee eee eeeeeeeee, eee ee eee eeeeeee eee ee eeee eee eeeeeee eeeeeee. Meee-eeeeeeeeeee eeee-eeeeeeeeeeeeeeeeee eeee eeeeee eeeeeee eeeeeeeee eeeeeeeeeee eeee (M)-88 [(M)-MMMM-MMMMMMM] ee eee eeeeee, eeeeeee eeee (M)-888 [(M)-Meeeeeeee] ee eeeeeeee ee eee eeeeee e eeeeeee eeeee ee eeeeeeeeee eee eeeeeeeeeee eeee eeee eeeeeeeeeeeeeeeeee eee eeeeeeee eeeeeeee eeeee (Meeee 8). Mee eeeeeeee eeeeeee eee eee ee M-eeeee eeeeee eeeeeee ee eeeeeeeeee (Meeee 8, eeeee 8), eeeee eeee eeeeeeee eee eeeeeeeee ee eeeee eeeeeee (eeeeeee 8–8). Mee eeeeeeee ee eee eeeeeeee eeeeeeee eeeee eee eeee eeeeeee eee eeeeeeeeeeeeeeeeee, ee eeee eee eeee ee eeeee eeeee, eeee eee eeee-eeeeeeeeeeeeeeeeee eeeee eeeeeee eeeeeee.
Meeee 8 Meeeeeeee(MM)-Meeeeeeee Meeeeeeeeeeeeeee Meeeeeeeeee ee Meeeee-8,8-eeeeee[888]
Meee eeeeeeeee-eeeeeeeee eeeeeeeeeee eeeeeeee ee e eee eeee ee eee eeeeeeeeee eeeee eeeeeeeee ee (−)-eeeeeeeeeeeee, e eeeeeee eeeeeeeeeeee-eeee eeeeeeeeeeeee. Meeeeeeeee ee eee eeee eeeeee eeee (M)-eeee eeeee 888, eeeeeeee ee eeeeeeeee(MM)-eeeeeeeee eeeeeeeeeee eeeeeee eee eeeeeeeeeeee 888 ee 88% eeeee eee eeee 88% eeeeeeeeeeee eeeeee, eeeee eee eeee eeeeeee eeeeeeeeeee eeee eee eeeeeee eeeeeee 888 (Meeeee 88).
Meeeee 88 Meeee Meeeeeeee ee (−)-Meeeeeeeeeeee ee Meeeeeeee(MM)-Meeeeeeee Meeeeeeeeee[888]
M eeeeeeeee eeeeeeee eee eeeeeeeeee ee Meeee eee ee-eeeeeee, eee eeee eeeeeeeee e eeeeeeeeeee eeeeeeee eeeeee eee eee eeeeeeeeee Meeee-eee eeeeeeee.[888] Mee eeeeeʼe eeeeeeee-eeeeeee eeeeeeeeeeee eeeeeeeee eee eeeeeeeee ee eeeeeeeeee eeeeeeee eeee B-eee eeeeee 888, ee eeee eeeeeeeeeeeeeeeeeeeeee 888. M eeeeee ee Meøeeeee eeee–Meeee eeee eeeeeeeeeeee eeee eeee eeeeeeeee, eee eee eeeeeeeeeee ee eeeeee(M) eeeeeeeeeeeeeeeeeeeeeeeee eeee eee ee eee eeeeeeeeeeee 8-eeeee-8-eeeeeeeeeeeeeeee-eeeeeee eeee eeeeeeeee 888 ee 888, ee e 88:8 eeeee eeeee, eeeeee eeeeeee eee eee eeeeeeeeee eeeeeeee. Meee eeeeeeeeee eee eeeeeeee eee eeeeeeeee eeeeeeee, eeeee eeeee ee ee eeeeeeee eeee eeee eee eeeeeeee eeeeeeeeeeee. Mee eeeeeeee eeeeeeeee eeeeeeee eeee ee eeeeeeeee eeeeeeeeeeeeeeeeee eee e eeeee ee B-eee eeeeee (Meeeee 88).
Meeeee 88 Meeeeeeeee Meeee-Mee Meeeeeee[888]
Meeeeeeeeeee Meeeeeeee
8,8-Meeeee-8-eeeeeeeeeeeeeeeeeeeeee 888; Meeeeee Meeeeeeee:[888]
Me e eeeeeeeeeeeee eeee eeee e eeeeeeee eeeeeee eee eee eeeee eeeeeeeee 888 (88–88 ee, 8 eeeee), Me8M (ee eeee e 8.88 M eeee), eeeeeee MeMM (88 eeeee), eee Me(MMe)8 (88 eee%) eeeeeeee ee Me{(M)-MMMM-MMMMMMM)}(MMe)8 (88 eee%). Mee eeeeeeee eee eeeeeeeee ee MMM eeeee eee eeeeeeee eeeeeeee eee eeeeeeee. Mee eeeeeee eee eeeeeeeeee eee eee eeeeee eeeeeee eee eeeeeeeeeeeeeee (eeeeeee/MeMMe) ee eeee eee eeeeeeee eeeeeee.
8-Meee-8-eeeeeeeeeeeeeeeeeeeeee 888; Meeeeee Meeeeeeee:[888]
M eeee ee eeeeeeeee 888 (8.88 eeee), MeMM (8 eeeee, 88 µM), eee Me{(M)-MMMM-MMMMMMM)}(MMe)8 (88 eee%) ee Me{(M)-Meeeeeeee}(MMe)8•8M8M (8 eee%) ee Me8M (8 eM) eee eeeeeee eeeee eee eeeeeeee eee eeeeeeee ee eeeeeeeeee ee MMM. Mee eeeeeee eee eeeeeee eee eee eeeeeee eee eeeeeeee (eeeeee eee) ee eeee eee eeeeeeee.
8,8-Meeeee-8-eeeeeeeeeeeeeeeeeeeeee 888; Meeeeee Meeeeeeee:[888]
Me e eeee ee [MeMMe]8•eeeeeee (8.8 ee, 8.888 eeee, 8.88 eeee MeMMe) eee eeeeeeeeee 888 (88 ee, 8.88 eeee) ee eee MM8Me8 (8 eM) eee eeeee B-eee eeeee 888 (8.8 eeee). Mee eeeeeee eee eeeeeee ee ee eeeee eeeeeeee eeeeeeeeeee ee eee B-eee eeeee eee eeeeeeeee ee MMM. Mee eeeeeee eee eeee eeeeeee eeeee eeeeeee eeeeeeee eee eee eeeeeeee eeeee eeeeeee eee eeeeeeee ee eeeee eeeeee eeeeeeeeeeeeee.
References